| Entry |
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| Name |
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| Class |
Isomerases;
Intramolecular transferases;
Transferring hydroxy groups
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| Sysname |
geraniol hydroxymutase
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| Reaction(IUBMB) |
geraniol = (3S)-linalool [RN: R09708]
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| Reaction(KEGG) |
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| Substrate |
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| Product |
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| Comment |
In absence of oxygen the bifunctional linalool dehydratase-isomerase can catalyse in vitro two reactions, the isomerization of (3S)-linalool to geraniol and the hydration of myrcene to (3S)-linalool, the latter activity being classified as EC 4.2.1.127, linalool dehydratase.
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| History |
EC 5.4.4.4 created 2011, modified 2012
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| Pathway |
| Monoterpenoid biosynthesis | | Biosynthesis of secondary metabolites |
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| Orthology |
| linalool dehydratase / geraniol isomerase |
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| Genes |
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| Reference |
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| Authors |
Brodkorb D, Gottschall M, Marmulla R, Luddeke F, Harder J |
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| Title |
Linalool dehydratase-isomerase, a bifunctional enzyme in the anaerobic degradation of monoterpenes. |
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| Journal |
J. Biol. Chem. 285 (2010) 30436-42. |
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| Sequence |
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| Reference |
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| Authors |
Luddeke F, Harder J |
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| Title |
Enantiospecific (S)-(+)-linalool formation from beta-myrcene by linalool dehydratase-isomerase. |
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| Journal |
Z. Naturforsch. C. 66 (2011) 409-12. |
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| Sequence |
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| Other DBs |
ExplorEnz - The Enzyme Database: IUBMB Enzyme Nomenclature: ExPASy - ENZYME nomenclature database: BRENDA, the Enzyme Database: |
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