KEGG   ENZYME: 3.2.1.125Help
Entry
EC 3.2.1.125                Enzyme                                 

Name
raucaffricine beta-glucosidase;
raucaffricine beta-D-glucosidase;
raucaffricine glucosidase
Class
Hydrolases;
Glycosylases;
Glycosidases, i.e. enzymes that hydrolyse O- and S-glycosyl compounds
BRITE hierarchy
Sysname
raucaffricine beta-D-glucohydrolase
Reaction(IUBMB)
raucaffricine + H2O = D-glucose + vomilenine [RN:R03703]
Reaction(KEGG)
Substrate
raucaffricine [CPD:C02074];
H2O [CPD:C00001]
Product
D-glucose [CPD:C00031];
vomilenine [CPD:C01761]
Comment
Highly specific; some other ajmalan glucoside alkaloids are hydrolysed, but more slowly.
Pathway
Indole alkaloid biosynthesis
Orthology
K12695  
raucaffricine beta-D-glucosidase
Reference
1
  Authors
Schubel, H., Stockigt, J., Feicht, R. and Simon, H.
  Title
Partial-purification and characterization of raucaffricine beta-D-glucosidase from plant cell-suspension cultures of Rauwolfia serpentina benth.
  Journal
Helv. Chim. Acta 69 (1986) 538-547.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
102925-37-1

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