KEGG   ENZYME: 1.13.11.73Help
Entry
EC 1.13.11.73               Enzyme                                 

Name
methylphosphonate synthase;
mpnS (gene name);
2-hydroxyethylphosphonate:O2 1,2-oxidoreductase (methylphosphonate forming)
Class
Oxidoreductases;
Acting on single donors with incorporation of molecular oxygen (oxygenases);
With incorporation of two atoms of oxygen
BRITE hierarchy
Sysname
2-hydroxyethylphosphonate:oxygen 1,2-oxidoreductase (methylphosphonate forming)
Reaction(IUBMB)
2-hydroxyethylphosphonate + O2 = methylphosphonate + HCO3- [RN:R10191]
Reaction(KEGG)
Substrate
2-hydroxyethylphosphonate [CPD:C06451];
O2 [CPD:C00007]
Product
methylphosphonate [CPD:C20396];
HCO3- [CPD:C00288]
Comment
Isolated from the marine archaeon Nitrosopumilus maritimus.
History
EC 1.13.11.73 created 2012
Pathway
Phosphonate and phosphinate metabolism
Orthology
K18049  
methylphosphonate synthase
Genes
NMR: 
Taxonomy
Reference
1  [PMID:22936780]
  Authors
Metcalf WW, Griffin BM, Cicchillo RM, Gao J, Janga SC, Cooke HA, Circello BT, Evans BS, Martens-Habbena W, Stahl DA, van der Donk WA
  Title
Synthesis of methylphosphonic acid by marine microbes: a source for methane in the aerobic ocean.
  Journal
Science. 337 (2012) 1104-7.
  Sequence
[nmr:Nmar_0155]
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 

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