KEGG   ENZYME: 1.14.99.33Help
Entry
EC 1.14.99.33               Enzyme                                 

Name
Delta12-fatty acid dehydrogenase;
crepenynate synthase;
linoleate Delta12-fatty acid acetylenase (desaturase)
Class
Oxidoreductases;
Acting on paired donors, with incorporation or reduction of molecular oxygen;
Miscellaneous
BRITE hierarchy
Sysname
linoleate, hydrogen-donor:oxygen oxidoreductase (Delta12-unsaturating)
Reaction(IUBMB)
linoleate + AH2 + O2 = crepenynate + A + 2 H2O [RN:R05740]
Reaction(KEGG)
Substrate
linoleate [CPD:C01595];
AH2 [CPD:C00030];
O2 [CPD:C00007]
Product
crepenynate [CPD:C07289];
A [CPD:C00028];
H2O [CPD:C00001]
Comment
Contains non-heme iron.
History
EC 1.14.99.33 created 2000
Pathway
Linoleic acid metabolism
Orthology
K08262  
delta12-fatty acid dehydrogenase
Genes
OLU: 
OTA: 
BPG: 
MIS: 
MPP: 
CME: 
TET: 
PTI: 
TPS: 
EHX: 
GTT: 
SYW: 
SYD: 
SYX: 
SYNR: 
PMA: 
Pro_1214(desA)
PMM: 
PMT: 
PMN: 
PMI: 
PMB: 
PMC: 
PMF: 
PMG: 
PMH: 
PMJ: 
PME: 
PRC: 
PRM: 
 » show all
Taxonomy
Reference
1
  Authors
Banas, A., Bafor, M., Wiberg, E., Lenman, M., Staahl, U. and Stymne, S.
  Title
Biosynthesis of an acetylenic fatty acid in microsomal preparations from developing seeds Crepis alpina.
  Journal
Physiol. Biochem. Mol. Biol. Plant. [Proc. Int. Symp. Plant Lipids] 12th (1997) 57-59.
Reference
2  [PMID:9572738]
  Authors
Lee M, Lenman M, Banas A, Bafor M, Singh S, Schweizer M, Nilsson R, Liljenberg C, Dahlqvist A, Gummeson PO, Sjodahl S, Green A, Stymne S.
  Title
Identification of non-heme diiron proteins that catalyze triple bond and epoxy group formation.
  Journal
Science. 280 (1998) 915-8.
  Sequence
[up:O81931]
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
197025-40-4

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