KEGG   ENZYME: 1.14.99.33Help
Entry
EC 1.14.99.33               Enzyme                                 
Name
Delta12-fatty acid dehydrogenase;
crepenynate synthase;
linoleate Delta12-fatty acid acetylenase (desaturase)
Class
Oxidoreductases;
Acting on paired donors, with O2 as oxidant and incorporation or reduction of oxygen. The oxygen incorporated need not be derived from O2;
Miscellaneous
BRITE hierarchy
Sysname
linoleate, hydrogen-donor:oxygen oxidoreductase (Delta12-unsaturating)
Reaction(IUBMB)
linoleate + AH2 + O2 = crepenynate + A + 2 H2O [RN:R05740]
Reaction(KEGG)
Substrate
linoleate [CPD:C01595];
AH2 [CPD:C00030];
O2 [CPD:C00007]
Product
crepenynate [CPD:C07289];
A [CPD:C00028];
H2O [CPD:C00001]
Comment
Contains non-heme iron.
Pathway
Linoleic acid metabolism
Orthology
K08262  
delta12-fatty acid dehydrogenase
Genes
OLU: 
OTA: 
CME: 
PTI: 
TPS: 
SYW: 
SYD: 
SYX: 
PMA: 
Pro1214(desA)
PMM: 
PMT: 
PMT0249
PMI: 
PMT9312_1476
PMB: 
A9601_15921
PMC: 
P9515_15601
PMF: 
P9303_21081
PMG: 
P9301_15761
PMH: 
P9215_16181(desA)
PMJ: 
P9211_06461 P9211_06471
PME: 
NATL1_10821
 » show all
Taxonomy
Reference
1
  Authors
Banas, A., Bafor, M., Wiberg, E., Lenman, M., Staahl, U. and Stymne, S.
  Title
Biosynthesis of an acetylenic fatty acid in microsomal preparations from developing seeds Crepis alpina.
  Journal
Physiol. Biochem. Mol. Biol. Plant. [Proc. Int. Symp. Plant Lipids] 12th (1997) 57-59.
Reference
2  [PMID:9572738]
  Authors
Lee M, Lenman M, Banas A, Bafor M, Singh S, Schweizer M, Nilsson R, Liljenberg C, Dahlqvist A, Gummeson PO, Sjodahl S, Green A, Stymne S.
  Title
Identification of non-heme diiron proteins that catalyze triple bond and epoxy group formation.
  Journal
Science. 280 (1998) 915-8.
  Organism
Arabidopsis thaliana [GN:ath]
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
197025-40-4
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