KEGG   ENZYME: 1.3.1.27Help
Entry
EC 1.3.1.27                 Enzyme                                 

Name
2-hexadecenal reductase;
2-alkenal reductase;
hexadecanal: NADP+ oxidoreductase
Class
Oxidoreductases;
Acting on the CH-CH group of donors;
With NAD+ or NADP+ as acceptor
BRITE hierarchy
Sysname
hexadecanal:NADP+ Delta2-oxidoreductase
Reaction(IUBMB)
hexadecanal + NADP+ = 2-trans-hexadecenal + NADPH + H+ [RN:R02463]
Reaction(KEGG)
Substrate
hexadecanal [CPD:C00517];
NADP+ [CPD:C00006]
Product
2-trans-hexadecenal [CPD:C06123];
NADPH [CPD:C00005];
H+ [CPD:C00080]
Comment
Specific for long chain 2-trans- and 2-cis-alkenals, with chain length optimum around 14 to 16 carbon atoms.
History
EC 1.3.1.27 created 1976
Reference
1  [PMID:4154890]
  Authors
Stoffel W, Darr W.
  Title
2-alkenal reductase isolation, properties and specificities.
  Journal
Hoppe. Seylers. Z. Physiol. Chem. 355 (1974) 54-60.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
52227-95-9

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