Entry
Name
chlorophyllide a reductase;
bchX (gene name);
bchY (gene name);
bchZ (gene name);
COR
Class
Oxidoreductases;
Acting on the CH-CH group of donors;
With an iron-sulfur protein as acceptor
BRITE hierarchy
Sysname
bacteriochlorophyllide-a:ferredoxin 7,8-oxidoreductase
Reaction(IUBMB)
(1) 3-deacetyl-3-vinylbacteriochlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster + ADP + phosphate = chlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + ATP + H2O + 2 H+ [RN:
R09053 ];
(2) bacteriochlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster + ADP + phosphate = 3-acetyl-3-devinylchlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + ATP + H2O + 2 H+;
(3) 3-deacetyl-3-(1-hydroxyethyl)bacteriochlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster + ADP + phosphate = 3-devinyl-3-(1-hydroxyethyl)chlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + ATP + H2O + 2 H+ [RN:
R09060 ]
Reaction(KEGG)
Substrate
3-deacetyl-3-vinylbacteriochlorophyllide a [CPD:
C18152 ];
oxidized ferredoxin [iron-sulfur] cluster [CPD:
C00139 ];
ADP [CPD:
C00008 ];
phosphate [CPD:
C00009 ];
bacteriochlorophyllide a [CPD:
C18155 ];
3-deacetyl-3-(1-hydroxyethyl)bacteriochlorophyllide a [CPD:
C18153 ]
Product
chlorophyllide a [CPD:
C02139 ];
reduced ferredoxin [iron-sulfur] cluster [CPD:
C00138 ];
ATP [CPD:
C00002 ];
H2O [CPD:
C00001 ];
H+ [CPD:
C00080 ];
3-acetyl-3-devinylchlorophyllide a;
3-devinyl-3-(1-hydroxyethyl)chlorophyllide a [CPD:
C18154 ]
Comment
The enzyme, together with EC
1.1.1.396 , bacteriochlorophyllide-a dehydrogenase, and EC
4.2.1.165 , chlorophyllide-a 31-hydratase, is involved in the conversion of chlorophyllide a to bacteriochlorophyllide a. These enzymes can act in multiple orders, resulting in the formation of different intermediates, but the final product of the cumulative action of the three enzymes is always bacteriochlorophyllide a. This enzyme catalyses a trans-reduction of the B-ring; the product has the (7R,8R)-configuration. In addition, the enzyme has a latent activity of EC
1.3.7.13 , 3,8-divinyl protochlorophyllide a 8-vinyl-reductase (ferredoxin) [4]. The enzyme contains a [4Fe-4S] cluster, and structurally resembles the Fe protein/MoFe protein complex of nitrogenase (EC
1.18.6.1 ), which catalyses an ATP-driven reduction.
History
EC 1.3.7.15 created 1965 as EC 1.3.99.35, modified 2012, transferred 2016 to EC 1.3.7.15
Pathway
ec01110 Biosynthesis of secondary metabolites
Orthology
K11333 3,8-divinyl chlorophyllide a/chlorophyllide a reductase subunit X
K11334 3,8-divinyl chlorophyllide a/chlorophyllide a reductase subunit Y
K11335 3,8-divinyl chlorophyllide a/chlorophyllide a reductase subunit Z
Genes
PAQM : E0F26_06830(bchZ) E0F26_06835(bchY) E0F26_06840
ALV : Alvin_2556 Alvin_2561 Alvin_2562
ATEP : Atep_25090 Atep_25140 Atep_25150
TVI : Thivi_2003 Thivi_2010 Thivi_2011
TMB : Thimo_3003 Thimo_3004 Thimo_3005
MPUR : MARPU_13265 MARPU_13270 MARPU_13275
TSY : THSYN_31095 THSYN_31100 THSYN_31105
TTP : E6P07_01740 E6P07_01745(bchY) E6P07_01790(bchZ)
THIP : N838_12395 N838_12400(bchY) N838_12405(bchZ)
CJAP : GWK36_12630(bchZ) GWK36_12635(bchY) GWK36_12640
THIM : KFB96_13090(bchZ) KFB96_13095(bchY) KFB96_13100
TBOG : LT988_08895(bchZ) LT988_08900(bchY) LT988_08905
TLR : Thiosp_04242(bchZ) Thiosp_04243(bchY) Thiosp_04244(bchX)
TFRI : Thiofri_00874(bchX) Thiofri_00875(bchY) Thiofri_00876(bchZ)
TWG : Thiowin_04452(bchZ) Thiowin_04453(bchY) Thiowin_04454(bchX)
HHA : Hhal_1608 Hhal_1609 Hhal_1610
HHK : HH1059_06270 HH1059_06280(bchY) HH1059_06290
HHC : M911_10340 M911_10345 M911_10350
EBS : ECTOBSL9_3044 ECTOBSL9_3045 ECTOBSL9_3046
PDQ : CL55_00013570 CL55_00013580 CL55_00013590
PANI : DCO16_03450(bchZ) DCO16_03455(bchY) DCO16_03460
PCOS : C2747_06945(bchZ) C2747_06950(bchY) C2747_06955
PWU : A8O14_08320 A8O14_08325 A8O14_08330
RAC : RA876_06000 RA876_06005 RA876_06010
LIM : L103DPR2_00972(nifH1) L103DPR2_00973(bchN_1) L103DPR2_00974(chlB_1)
LIH : L63ED372_00628(nifH1) L63ED372_00629(bchN_1) L63ED372_00630(chlB)
HYR : BSY239_1379(bchZ) BSY239_1380(bchY) BSY239_1381
HCZ : G9Q37_00130 G9Q37_00135(bchY) G9Q37_00140(bchZ)
METP : C1M51_03565(bchZ) C1M51_03570(bchY) C1M51_03575
RGE : RGE_33680(bchZ) RGE_33690(bchY) RGE_33700(bchX)
RBN : RBXJA2T_09442 RBXJA2T_09447 RBXJA2T_09452
RDP : RD2015_1037 RD2015_1038 RD2015_1039
ROI : N4261_01205 N4261_01210(bchY) N4261_01215(bchZ)
ATER : MW290_02510(bchZ) MW290_02515(bchY) MW290_02520
METR : BSY238_2448 BSY238_2449(bchY) BSY238_2450(bchZ)
BEB : AEM42_07475 AEM42_07480 AEM42_07485
RPOD : E0E05_11790 E0E05_11795(bchY) E0E05_11800(bchZ)
AGC : BSY240_3666(bchZ) BSY240_3667(bchY) BSY240_3668
RROS : D4A92_02635 D4A92_02640(bchY) D4A92_02645(bchZ)
ABAW : D5400_04820(bchZ) D5400_04825(bchY) D5400_04830
PDES : FE840_002325 FE840_002330(bchY) FE840_002335(bchZ)
BRA : BRADO1618(bchX) BRADO1619(bchY) BRADO1620(bchZ)
BBT : BBta_6435(bchZ) BBta_6436(bchY) BBta_6437(bchX)
BRS : S23_19180(bchX) S23_19190(bchY) S23_19200(bchZ)
AOL : S58_59160 S58_59170 S58_59180
BRO : BRAD285_5779(bchZ) BRAD285_5780(bchY) BRAD285_5781(bchX)
BRQ : CIT40_23930(bchZ) CIT40_23935(bchY) CIT40_23940
BGZ : XH91_02645 XH91_02650(bchY) XH91_02655(bchZ)
BBET : F8237_24675 F8237_24680(bchY) F8237_24685(bchZ)
BROS : QUH67_09835 QUH67_09840(bchY) QUH67_09845(bchZ)
RPA : TX73_007825 TX73_007830(bchY) TX73_007835(bchZ)
RPB : RPB_3999 RPB_4000 RPB_4001
RPC : RPC_1293 RPC_1294 RPC_1295
RPD : RPD_3754 RPD_3755 RPD_3756
RPE : RPE_1327 RPE_1328 RPE_1329
RPT : Rpal_1710 Rpal_1711 Rpal_1712
RPX : Rpdx1_3996 Rpdx1_3997 Rpdx1_3998
BOS : BSY19_4053(bchZ) BSY19_4054(bchY) BSY19_4055
MEA : Mex_1p2927(bchX) Mex_1p2928(bchY) Mex_1p2929(bchZ)
MDI : METDI3496(bchX) METDI3497(bchY) METDI3498(bchZ)
MEX : Mext_2730 Mext_2731 Mext_2732
MCH : Mchl_2957 Mchl_2958 Mchl_2959
MPO : Mpop_2852 Mpop_2853 Mpop_2854
MZA : B2G69_21190 B2G69_21195 B2G69_21200
MRD : Mrad2831_2816 Mrad2831_2817 Mrad2831_2818
MET : M446_3697 M446_3698 M446_3699
MOR : MOC_3181(bchZ) MOC_3182(bchY) MOC_3183
META : Y590_13140 Y590_13145 Y590_13150
MAQU : Maq22A_1p32545(nifH) Maq22A_1p32550 Maq22A_1p32555(nifD)
MPHY : MCBMB27_02257 MCBMB27_02258 MCBMB27_02259
MEE : DA075_03960 DA075_03965(bchY) DA075_03970(bchZ)
METD : C0214_15305 C0214_15310(bchY) C0214_15315(bchZ)
METX : A3862_17700 A3862_17705 A3862_17710
METS : DK389_31425(bchZ) DK389_31430(bchY) DK389_31435
METI : DK427_17885(bchZ) DK427_17890(bchY) DK427_17895
MMES : MMSR116_13615 MMSR116_13620(bchY) MMSR116_13625(bchZ)
MTEA : DK419_04920 DK419_04925(bchY) DK419_04930(bchZ)
MIND : mvi_08980 mvi_08990(bchY) mvi_09000
MOG : MMB17_23875(bchZ) MMB17_23880(bchY) MMB17_23885
MTAD : M6G65_16615(bchZ) M6G65_16620(bchY) M6G65_16625
MSL : Msil_2052 Msil_2053 Msil_2054
BBAR : RHAL1_03012(bchZ) RHAL1_03013(bchY) RHAL1_03014(bchX)
RVA : Rvan_0210 Rvan_0211 Rvan_0212
RLAC : QMO75_01210 QMO75_01215(bchY) QMO75_01220(bchZ)
BVR : BVIR_599 BVIR_600 BVIR_601
BLAG : BLTE_02350 BLTE_02360 BLTE_02370
MROS : EHO51_17035 EHO51_17040(bchY) EHO51_17045(bchZ)
CMET : K6K41_01675 K6K41_01680(bchY) K6K41_01685(bchZ)
AUZ : Sa4125_27730 Sa4125_27740 Sa4125_27750
AUB : LXB15_06370(bchZ) LXB15_06375(bchY) LXB15_06380
JIE : OH818_18145(bchZ) OH818_18150(bchY) OH818_18155
BSB : Bresu_3043 Bresu_3044 Bresu_3045
BRL : BZG35_15445 BZG35_15450 BZG35_15455
BREA : HZ989_04595 HZ989_04600(bchY) HZ989_04605(bchZ)
RUT : FIU92_10145(chlB) FIU92_10150 FIU92_10155(nifH1)
JAN : Jann_0177(bchZ) Jann_0178(bchY) Jann_0179(bchX)
RDE : RD1_0109(bchZ) RD1_0110(bchY) RD1_0111(bchX)
RLI : RLO149_p940160(bchX) RLO149_p940170(bchY) RLO149_p940180(bchZ)
RPON : G3256_18660 G3256_18670(bchY) G3256_18675(bchZ)
DSH : Dshi_3517(bchX) Dshi_3518(bchY) Dshi_3519(bchZ)
RED : roselon_01078 roselon_01079 roselon_01080
SUAM : BOO69_19400 BOO69_19405 BOO69_19410
SUAL : KDD17_18360 KDD17_18365(bchY) KDD17_18370(bchZ)
TOM : BWR18_20240 BWR18_20250 BWR18_20255
RMM : ROSMUCSMR3_00902(bchZ) ROSMUCSMR3_00903(bchY) ROSMUCSMR3_00905(bchX)
ROK : RAK1035_3771 RAK1035_3772 RAK1035_3774
RID : RIdsm_01755(nifH1) RIdsm_01757 RIdsm_01758(chlB)
ROM : EI983_05440 EI983_05445(bchY) EI983_05450(bchZ)
ROH : FIU89_14220(chlB) FIU89_14225 FIU89_14235(nifH1)
THAA : CFI11_23550 CFI11_23555(bchY) CFI11_23560(bchZ)
ROT : FIV09_18070(nifH1) FIV09_18075 FIV09_18080(chlB)
RMH : LVO79_17420 LVO79_17425(bchY) LVO79_17430(bchZ)
MALU : KU6B_16430(bchX) KU6B_16440(bchY) KU6B_16450(bchZ)
PLCG : RVY76_13940 RVY76_13945(bchY) RVY76_13950(bchZ)
MARU : FIU81_13850(chlB) FIU81_13855(chlN) FIU81_13860(nifH1)
RMAI : MACH21_32790(bchX) MACH21_32800(bchY) MACH21_32810(bchZ)
RSP : RSP_0260(bchZ) RSP_0261(bchY) RSP_0262(bchX)
RSH : Rsph17029_1904 Rsph17029_1905 Rsph17029_1906
RSQ : Rsph17025_2034 Rsph17025_2035 Rsph17025_2036
RSK : RSKD131_1587 RSKD131_1588 RSKD131_1589
CAZT : LV780_09065(bchZ) LV780_09070(bchY) LV780_09075
RCP : RCAP_rcc00687(bchX) RCAP_rcc00688(bchY) RCAP_rcc00689(bchZ)
RBL : B6K69_00190 B6K69_00195 B6K69_00200
PTP : RCA23_c29620(bchX) RCA23_c29630(bchY) RCA23_c29640(bchZ)
RSU : NHU_04287(bchX) NHU_04289(bchY) NHU_04290(bchZ)
RHM : B5V46_17475 B5V46_17480 B5V46_17485
RHC : RGUI_1959 RGUI_1960 RGUI_1961
LVS : LOKVESSMR4R_03679(bchX) LOKVESSMR4R_03680(bchY) LOKVESSMR4R_03681(bchZ)
RBG : BG454_03035 BG454_03040(bchY) BG454_03045(bchZ)
GEH : HYN69_05525 HYN69_05530(bchY) HYN69_05535(bchZ)
TAW : EI545_18945 EI545_18950(bchY) EI545_18955(bchZ)
POZ : I0K15_00010 I0K15_20930(bchZ)
NSM : JO391_16465 JO391_16470(bchY) JO391_16475(bchZ)
PBAE : P8S53_17225 P8S53_17230(bchY) P8S53_17235(bchZ)
FAQ : G5B39_11870(bchZ) G5B39_11875(bchY) G5B39_11880
RBX : I3V23_09390 I3V23_09395(bchY) I3V23_09400(bchZ)
HBC : AEM38_14575 AEM38_14580 AEM38_14585
NOT : C7W88_00480 C7W88_00490(bchZ)
NGF : FRF71_09145 FRF71_09150(bchY) FRF71_09155(bchZ)
NOG : GKE62_08435 GKE62_08440(bchY) GKE62_08445(bchZ)
SPHI : TS85_22905 TS85_22910 TS85_22915
SSAN : NX02_18440 NX02_18445 NX02_18450
SCHY : GVO57_11620(bchZ) GVO57_11625(bchY) GVO57_11630
SGLC : M1K48_13795(bchZ) M1K48_13800(bchY) M1K48_13805
SQO : NMP03_02120 NMP03_02125(bchY) NMP03_02130(bchZ)
SRAD : LLW23_12145 LLW23_12150(bchY) LLW23_12155(bchZ)
CIJ : WG74_05045 WG74_05050 WG74_05055
SLAA : EUU25_10270 EUU25_10275(bchY) EUU25_10280(bchZ)
BLAS : BSY18_3555 BSY18_3556(bchY) BSY18_3557(bchZ)
BFW : B5J99_08570 B5J99_08575 B5J99_08580
PALG : HFP57_06940(bchZ) HFP57_06945(bchY) HFP57_06950
PARJ : J4G78_07525(bchZ) J4G78_07530(bchY) J4G78_07535
SAND : H3309_05750 H3309_05755(bchY) H3309_05760(bchZ)
POQ : KZX46_18695(bchZ) KZX46_18700(bchY) KZX46_18705
PMEA : KTC28_17005(bchZ) KTC28_17010(bchY) KTC28_17015
ALH : G6N82_11430 G6N82_11435(bchY) G6N82_11440(bchZ)
ARUE : QQX03_04210 QQX03_04215(bchY) QQX03_04220(bchZ)
ELQ : Ga0102493_111836 Ga0102493_111837 Ga0102493_111838
ERK : CD351_13870 CD351_13875(bchY) CD351_13880(bchZ)
ERF : FIU90_13830(nifH1) FIU90_13835 FIU90_13840(chlB1)
PNS : A9D12_01290 A9D12_01295 A9D12_01300
PORL : BG023_112670 BG023_112671 BG023_112672
PHZ : CHX26_14500 CHX26_14505(bchY) CHX26_14510(bchZ)
POT : E2E27_07325(bchZ) E2E27_07330(bchY) E2E27_07335
AMV : ACMV_18770(bchZ) ACMV_18780(bchY) ACMV_18790(bchX)
RFL : Rmf_22230 Rmf_22240(bchY) Rmf_22250
SRF : LHU95_13855 LHU95_13860(bchY) LHU95_13865(bchZ)
RAP : RHOA_2428(bchX) RHOA_2429(bchY) RHOA_2430(bchZ)
NCB : C0V82_18155(bchZ) C0V82_18160(bchY) C0V82_18165
SKT : IGS68_17105(bchZ) IGS68_17110(bchY) IGS68_17115
SMUC : JL100_008920 JL100_008925(bchY) JL100_008930(bchZ)
SROE : JL101_015285(bchZ) JL101_015290(bchY) JL101_015295
RRU : Rru_A2978 Rru_A2979 Rru_A2980
RRF : F11_15255 F11_15260 F11_15265
RCE : RC1_2094(bchX) RC1_2095(bchY) RC1_2096(bchZ)
RPM : RSPPHO_01498(bchZ) RSPPHO_01499(bchY) RSPPHO_01500
ELIO : KO353_03065(bchZ) KO353_03070(bchY) KO353_03075
THAR : T8K17_11765 T8K17_11770(bchY) T8K17_11775(bchZ)
HMO : HM1_0654(bchY) HM1_0655(bchZ) HM1_0659(bchX)
HCV : FTV88_2670(bchX) FTV88_2673(bchZ) FTV88_2674(bchY)
RRS : RoseRS_3256 RoseRS_3257 RoseRS_3260
RCA : Rcas_3743 Rcas_3744 Rcas_3746
CAU : Caur_0417 Caur_3805 Caur_3806
CHL : Chy400_0444 Chy400_4108 Chy400_4109
CAG : Cagg_0850 Cagg_0851 Cagg_3127
VAB : WPS_26170 WPS_26180 WPS_26190
CTM : Cabther_A0934 Cabther_A1527 Cabther_A1571
CVL : J8C06_01345 J8C06_07320 J8C06_09555
CHLO : J8C02_04520 J8C02_07535 J8C02_07755
GPH : GEMMAAP_06510 GEMMAAP_06515 GEMMAAP_06520
GGR : HKW67_08765 HKW67_08770(bchY) HKW67_08775(bchZ)
CTE : CT1423(bchX) CT1826(bchY) CT2125(bchZ)
CPC : Cpar_0119 Cpar_0375 Cpar_0741
CLZ : BIU88_03600 BIU88_09875 BIU88_11835
CCH : Cag_0324 Cag_0400 Cag_1716
CPH : Cpha266_1792 Cpha266_2075 Cpha266_2500
CPB : Cphamn1_0173 Cphamn1_0937 Cphamn1_2062
CLI : Clim_0157 Clim_0897 Clim_2035
PVI : Cvib_0191 Cvib_0407 Cvib_1241
PLT : Plut_0124 Plut_0342 Plut_1423
PPH : Ppha_0177 Ppha_0979 Ppha_2411
PAA : Paes_0168 Paes_1535 Paes_1863
PROC : Ptc2401_00130(bchB_1) Ptc2401_00667(nifH1_1) Ptc2401_01952
PRS : B9H02_00755 B9H02_04010
PROS : CHL67_00825(bchZ) CHL67_03600 CHL67_09910(bchY)
PROW : OO006_00825(bchZ) OO006_02340(bchY) OO006_08985
PROI : OO005_00790(bchZ) OO005_02305(bchY) OO005_08285
CTS : Ctha_0198 Ctha_0817 Ctha_2720
» show all
Taxonomy
Reference
Authors
Nomata J, Mizoguchi T, Tamiaki H, Fujita Y
Title
A second nitrogenase-like enzyme for bacteriochlorophyll biosynthesis: reconstitution of chlorophyllide a reductase with purified X-protein (BchX) and YZ-protein (BchY-BchZ) from Rhodobacter capsulatus.
Journal
Sequence
Reference
Authors
Tsukatani Y, Yamamoto H, Harada J, Yoshitomi T, Nomata J, Kasahara M, Mizoguchi T, Fujita Y, Tamiaki H
Title
An unexpectedly branched biosynthetic pathway for bacteriochlorophyll b capable of absorbing near-infrared light.
Journal
Reference
Authors
Lange C, Kiesel S, Peters S, Virus S, Scheer H, Jahn D, Moser J
Title
Broadened Substrate Specificity of 3-Hydroxyethyl Bacteriochlorophyllide a Dehydrogenase (BchC) Indicates a New Route for the Biosynthesis of Bacteriochlorophyll a.
Journal
Reference
Authors
Harada J, Mizoguchi T, Tsukatani Y, Yokono M, Tanaka A, Tamiaki H
Title
Chlorophyllide a oxidoreductase works as one of the divinyl reductases specifically involved in bacteriochlorophyll a biosynthesis.
Journal
Other DBs
ExplorEnz - The Enzyme Database: 1.3.7.15
ExPASy - ENZYME nomenclature database: 1.3.7.15