KEGG   ENZYME: 1.4.3.12Help
Entry
EC 1.4.3.12                 Enzyme                                 

Name
cyclohexylamine oxidase
Class
Oxidoreductases;
Acting on the CH-NH2 group of donors;
With oxygen as acceptor
BRITE hierarchy
Sysname
cyclohexylamine:oxygen oxidoreductase (deaminating)
Reaction(IUBMB)
cyclohexylamine + O2 + H2O = cyclohexanone + NH3 + H2O2 [RN:R02233]
Reaction(KEGG)
R02233;
(other) R06133
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Substrate
cyclohexylamine [CPD:C00571];
O2 [CPD:C00007];
H2O [CPD:C00001]
Product
cyclohexanone [CPD:C00414];
NH3 [CPD:C00014];
H2O2 [CPD:C00027]
Comment
A flavoprotein (FAD). Some other cyclic amines can act instead of cyclohexylamine, but not simple aliphatic and aromatic amides.
History
EC 1.4.3.12 created 1978
Pathway
Caprolactam degradation
Microbial metabolism in diverse environments
Reference
1  [PMID:18451]
  Authors
Tokieda T, Niimura T, Takamura F, Yamaha T.
  Title
Purification and some properties of cyclohexylamine oxidase from a Pseudomonas sp.
  Journal
J. Biochem. (Tokyo). 81 (1977) 851-8.
  Organism
Pseudomonas sp.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
UM-BBD (Biocatalysis/Biodegradation Database): 
BRENDA, the Enzyme Database: 
CAS: 
63116-97-2

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