KEGG   ENZYME: 2.1.1.94Help
Entry
EC 2.1.1.94                 Enzyme                                 

Name
tabersonine 16-O-methyltransferase;
11-demethyl-17-deacetylvindoline 11-methyltransferase;
11-O-demethyl-17-O-deacetylvindoline O-methyltransferase;
S-adenosyl-L-methionine:11-O-demethyl-17-O-deacetylvindoline 11-O-methyltransferase
Class
Transferases;
Transferring one-carbon groups;
Methyltransferases
BRITE hierarchy
Sysname
S-adenosyl-L-methionine:16-hydroxytabersonine 16-O-methyltransferase
Reaction(IUBMB)
S-adenosyl-L-methionine + 16-hydroxytabersonine = S-adenosyl-L-homocysteine + 16-methoxytabersonine [RN:R05885]
Reaction(KEGG)
R05885;
(other) R03229
Show
Substrate
S-adenosyl-L-methionine [CPD:C00019];
16-hydroxytabersonine [CPD:C11643]
Product
S-adenosyl-L-homocysteine [CPD:C00021];
16-methoxytabersonine [CPD:C11675]
Comment
Involved in the biosynthesis of vindoline from tabersonine in the Madagascar periwinkle, Catharanthus roseus.
History
EC 2.1.1.94 created 1989, modified 2005
Pathway
Indole alkaloid biosynthesis
Reference
1
  Authors
De Luca, V., Balsevich, J., Tyler, R.T., Eilert, U., Panchuk, B.D. and Kurz, W.G.W.
  Title
Biosynthesis of indole alkaloids - developmental regulation of the biosynthetic-pathway from tabersonine to vindoline in Catharanthus roseus.
  Journal
J. Plant Physiol. 125 (1986) 147-156.
Reference
2
  Authors
Fahn, W., Laussermair, E., Deus-Neumann, B. and Stockigt, J.
  Title
Late enzymes of vindoline biosynthesis. S-Adenosyl-L-methionine:11-O-demethyl-17-O-deacetylvindoline 11-O-methylase and unspecific acetylesterase.
  Journal
Plant Cell Rep. 4 (1985) 337-340.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
100984-95-0

DBGET integrated database retrieval system