KEGG   ENZYME: 2.3.1.152Help
Entry
EC 2.3.1.152                Enzyme                                 

Name
alcohol O-cinnamoyltransferase
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
BRITE hierarchy
Sysname
1-O-trans-cinnamoyl-beta-D-glucopyranose:alcohol O-cinnamoyltransferase
Reaction(IUBMB)
1-O-trans-cinnamoyl-beta-D-glucopyranose + ROH = alkyl cinnamate + glucose [RN:R04411]
Reaction(KEGG)
Substrate
1-O-trans-cinnamoyl-beta-D-glucopyranose [CPD:C04164];
ROH [CPD:C01335]
Product
alkyl cinnamate [CPD:C06357];
glucose [CPD:C00031]
Comment
Acceptor alcohols (ROH) include methanol, ethanol and propanol. No cofactors are required as 1-O-trans-cinnamoyl-beta-D-glucopyranose itself is an "energy-rich" (activated) acyl-donor, comparable to CoA-thioesters. 1-O-trans-Cinnamoyl-beta-D-gentobiose can also act as the acyl donor, but with much less affinity.
History
EC 2.3.1.152 created 1999
Reference
1
  Authors
Mock, H.-P., Strack, D.
  Title
Energetics of uridine 5'-diphosphoglucose-hydroxy-cinnamic acid acyl-glucotransferase reaction.
  Journal
Phytochemistry 32 (1993) 575-579.
Reference
2
  Authors
Latza, S., Gansser, D., Berger, R.G.
  Title
Carbohydrate esters of cinnamic acid from fruits of Physalis peruviana, Psidium guajava and Vaccinium vitis IDAEA.
  Journal
Phytochemistry 43 (1996) 481-485.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
203009-15-8

DBGET integrated database retrieval system