KEGG   ENZYME: 2.3.1.232Help
Entry
EC 2.3.1.232                Enzyme                                 

Name
methanol O-anthraniloyltransferase;
AMAT;
anthraniloyl-coenzyme A (CoA):methanol acyltransferase
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
BRITE hierarchy
Sysname
anthraniloyl-CoA:methanol O-anthraniloyltransferase
Reaction(IUBMB)
anthraniloyl-CoA + methanol = CoA + O-methyl anthranilate [RN:R10681]
Reaction(KEGG)
Substrate
anthraniloyl-CoA [CPD:C02247];
methanol [CPD:C00132]
Product
CoA [CPD:C00010];
O-methyl anthranilate [CPD:C20634]
Comment
The enzyme from Concord grape (Vitis labrusca) is solely responsible for the production of O-methyl anthranilate, an important aroma and flavor compound in the grape. The enzyme has a broad substrate specificity, and can use a range of alcohols with substantial activity, the best being butanol, benzyl alcohol, iso-pentanol, octanol and 2-propanol. It can use benzoyl-CoA and acetyl-CoA as acyl donors with lower efficiency. In addition to O-methyl anthranilate, the enzyme might be responsible for the production of ethyl butanoate, methyl-3-hydroxy butanoate and ethyl-3-hydroxy butanoate, which are present in large quantities in the grapes. Also catalyses EC 2.3.1.196, benzyl alcohol O-benzoyltransferase.
History
EC 2.3.1.232 created 2014
Orthology
K19861  
benzyl alcohol O-benzoyltransferase
Genes
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Lj0g3v0036889.1(Lj0g3v0036889.1) Lj0g3v0036899.1(Lj0g3v0036899.1) Lj0g3v0074289.1(Lj0g3v0074289.1) Lj0g3v0158209.1(Lj0g3v0158209.1) Lj0g3v0189009.1(Lj0g3v0189009.1) Lj0g3v0272449.1(Lj0g3v0272449.1) Lj0g3v0302449.1(Lj0g3v0302449.1) Lj0g3v0315379.1(Lj0g3v0315379.1) Lj0g3v0363569.1(Lj0g3v0363569.1) Lj1g3v4955540.1(Lj1g3v4955540.1) Lj2g3v0483910.1(Lj2g3v0483910.1) Lj3g3v1957940.1(Lj3g3v1957940.1) Lj3g3v1959040.1(Lj3g3v1959040.1) Lj3g3v2095960.1(Lj3g3v2095960.1) Lj3g3v2095960.2(Lj3g3v2095960.2) Lj4g3v2604010.1(Lj4g3v2604010.1) Lj4g3v2604020.1(Lj4g3v2604020.1) Lj4g3v2881970.1(Lj4g3v2881970.1)
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DOSA: 
Os01t0350000-01(Os01g0350000) Os04t0507400-00(Os04g0507400) Os05t0141300-00(Os05g0141300) Os05t0155800-00(Os05g0155800) Os05t0289700-01(Os05g0289700) Os05t0315700-00(Os05g0315700) Os06t0710700-01(Os06g0710700) Os07t0244200-01(Os07g0244200) Os07t0421600-00(Os07g0421600) Os07t0550600-01(Os07g0550600) Os10t0105850-00(Os10g0105850) Os10t0133500-01(Os10g0133500) Os10t0195600-01(Os10g0195600) Os11t0268300-00(Os11g0268300)
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 » show all
Taxonomy
Reference
1  [PMID:16262710]
  Authors
Wang J, De Luca V
  Title
The biosynthesis and regulation of biosynthesis of Concord grape fruit esters, including 'foxy' methylanthranilate.
  Journal
Plant. J. 44 (2005) 606-19.
  Sequence
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 

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