KEGG   ENZYME: 2.5.1.34Help
Entry
EC 2.5.1.34                 Enzyme                                 
Name
4-dimethylallyltryptophan synthase;
dimethylallylpyrophosphate:L-tryptophan dimethylallyltransferase;
dimethylallyltryptophan synthetase;
dimethylallylpyrophosphate:tryptophan dimethylallyl transferase;
DMAT synthetase;
4-(gamma,gamma-dimethylallyl)tryptophan synthase;
tryptophan dimethylallyltransferase
Class
Transferases;
Transferring alkyl or aryl groups, other than methyl groups;
Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
BRITE hierarchy
Sysname
dimethylallyl-diphosphate:L-tryptophan 4-dimethylallyltransferase
Reaction(IUBMB)
dimethylallyl diphosphate + L-tryptophan = diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan [RN:R01657]
Reaction(KEGG)
R01657;
(other) R02943
Show
Substrate
dimethylallyl diphosphate [CPD:C00235];
L-tryptophan [CPD:C00078]
Product
diphosphate [CPD:C00013];
4-(3-methylbut-2-enyl)-L-tryptophan [CPD:C04290]
Orthology
K14130  
tryptophan 4-dimethylallyltransferase
Genes
AFM: 
AOR: 
AOR_1_1880174(AO090005001079)
AFV: 
ACT: 
ABE: 
TVE: 
Taxonomy
Reference
1  [PMID:999297]
  Authors
Lee SL, Floss HG, Heinstein P.
  Title
Purification and properties of dimethylallylpyrophosphate:tryptopharm dimethylallyl transferase, the first enzyme of ergot alkaloid biosynthesis in Claviceps. sp. SD 58.
  Journal
Arch. Biochem. Biophys. 177 (1976) 84-94.
  Organism
Claviceps. sp.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
55127-01-0
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