KEGG   ENZYME: 5.3.99.6Help
Entry
EC 5.3.99.6                 Enzyme                                 

Name
allene-oxide cyclase
Class
Isomerases;
Intramolecular oxidoreductases;
Other intramolecular oxidoreductases
BRITE hierarchy
Sysname
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate isomerase (cyclizing)
Reaction(IUBMB)
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate = (15Z)-12-oxophyto-10,15-dienoate [RN:R03402]
Reaction(KEGG)
Substrate
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate [CPD:C04672]
Product
(15Z)-12-oxophyto-10,15-dienoate [CPD:C01226]
Comment
Allene oxides formed by the action of EC 4.2.1.92 hydroperoxide dehydratase, are converted into cyclopentenone derivatives.
History
EC 5.3.99.6 created 1992
Pathway
alpha-Linolenic acid metabolism
Metabolic pathways
Biosynthesis of secondary metabolites
Orthology
K10525  
allene oxide cyclase
Genes
ATH: 
AT1G13280(AOC4) AT3G25760(AOC1) AT3G25770(AOC2) AT3G25780(AOC3)
ALY: 
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GMX: 
100775373(AOC1) 100795498(AOC3) 100800036(AOC2) 100803536(AOC5) 100803666(AOC4) 100805194(AOC6)
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VVI: 
SLY: 
544306(aoc)
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SIND: 
BVG: 
NNU: 
OSA: 
4333201(aoc)
DOSA: 
Os03t0438100-01(Os03g0438100)
OBR: 
BDI: 
SBI: 
SORBI_01g031870(SORBIDRAFT_01g031870)
ZMA: 
100273356(GRMZM2G415793) 542151(aoc1)
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 » show all
Taxonomy
Reference
1  [PMID:3178850]
  Authors
Hamberg M.
  Title
Biosynthesis of 12-oxo-10,15(Z)-phytodienoic acid: identification of an allene oxide cyclase.
  Journal
Biochem. Biophys. Res. Commun. 156 (1988) 543-50.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
118390-59-3

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