| Entry |
|
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| Name |
phosphoenolpyruvate mutase;
phosphoenolpyruvate-phosphonopyruvate phosphomutase;
PEP phosphomutase;
phosphoenolpyruvate phosphomutase;
PEPPM;
PEP phosphomutase
|
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| Class |
Isomerases;
Intramolecular transferases;
Phosphotransferases (phosphomutases)
 |
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| Sysname |
phosphoenolpyruvate 2,3-phosphonomutase
|
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| Reaction(IUBMB) |
phosphoenolpyruvate = 3-phosphonopyruvate [RN: R00661]
|
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| Reaction(KEGG) |
|
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| Substrate |
phosphoenolpyruvate [CPD: C00074]
|
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| Product |
3-phosphonopyruvate [CPD: C02798]
|
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| Comment |
Involved in the biosynthesis of the C-P bond, although the equilibrium greatly favours phosphoenolpyruvate.
|
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| Pathway |
| Phosphonate and phosphinate metabolism | | Metabolic pathways | | Biosynthesis of secondary metabolites | | Microbial metabolism in diverse environments |
|
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| Orthology |
| phosphoenolpyruvate phosphomutase |
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| Genes |
NVE: | | HMG: | | TET: | | PTM: | | TCR: | | ECA: | | PCT: | | PCC: | | PWA: | | PEC: | | PLU: | | EIC: | | HDE: | | PAM: | | PLF: | | PAJ: | | PAQ: | | VFI: | | PFL: | | PFC: | | PPZ: | | PEN: | | SDN: | | NOC: | | NHL: | | NWA: | | RME: | | BMA: | | BMV: | | BML: | | BMN: | | BPS: | | BPM: | | BPL: | | BPD: | | BPZ: | | BPQ: | | BTE: | | BVI: | | BUR: | | BCN: | | BCH: | | BCM: | | BCJ: | | BAM: | | BAC: | | BMU: | | BMJ: | | BCT: | | BXE: | | BPH: | | BPY: | | BGL: | | BUG: | | BGE: | | BGF: | | BRH: | | BGD: | | BYI: | | BUK: | | BPX: | | BPAR: | | BBR: | | BBM: | | BBH: | | AXY: | | AAV: | | AAA: | | AZO: | | HCP: | | HCB: | | CJU: | | ANT: | | NSA: | | PCA: | | PPD: | | DAK: | | DAL: | | SCL: | | DAO: | | MLO: | | SMK: | | ARA: | | AVI: | | RTR: | | RPC: | | AOL: | | TMO: | | BSS: | | BSUB: | | BYA: | | BQY: | | BMQ: | | BMD: | | BMH: | | PPY: | | PTA: | | SNX: | | CTC: | | CBJ: | | CBE: | | CSR: | | CLE: | | RIX: | | RAL: | | RCH: | | HAS: | | SSG: | | NBR: | | SDV: | | KSK: | | FRA: | | FAL: | | SAQ: | | SNA: | | AYM: | | OLS: | | TDE: | | TBE: | | TAZ: | | TPI: | | SSM: | | STA: | | SCD: | | TPX: | | BIP: | | SBU: | | SGP: | | BTH: | | BFR: | | BFS: | | BFG: | | FSU: | | FSC: | | ARP: | | NDE: | | TAR: | | NMR: | |
» show all
 |
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| Reference |
1 |
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| Authors |
Bowman, E., McQueney, M., Barry, R.J. and Dunaway-Mariano, D. |
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| Title |
Catalysis and thermodynamics of the phosphoenolpyruvate phosphonopyruvate rearrangement - entry into the phosphonate class of naturally-occurring organo-phosphorus compounds. |
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| Journal |
J. Am. Chem. Soc. 110 (1988) 5575-5576. |
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| Reference |
|
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| Authors |
Hidaka T, Imai S, Hara O, Anzai H, Murakami T, Nagaoka K, Seto H. |
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| Title |
Carboxyphosphonoenolpyruvate phosphonomutase, a novel enzyme catalyzing C-P bond formation. |
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| Journal |
J. Bacteriol. 172 (1990) 3066-72. |
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| Organism |
Streptomyces hygroscopicus |
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| Reference |
|
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| Authors |
Seidel HM, Freeman S, Seto H, Knowles JR. |
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| Title |
Phosphonate biosynthesis: isolation of the enzyme responsible for the formation of a carbon-phosphorus bond. |
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| Journal |
Nature. 335 (1988) 457-8. |
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| Organism |
Tetrahymena pyriformis |
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| Sequence |
|
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| Other DBs |
ExplorEnz - The Enzyme Database: IUBMB Enzyme Nomenclature: ExPASy - ENZYME nomenclature database: BRENDA, the Enzyme Database: CAS: 115756-49-5 |
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