KEGG   ENZYME: 5.4.99.48Help
Entry
EC 5.4.99.48                Enzyme                                 
Name
achilleol B synthase
Class
Isomerases;
Intramolecular transferases;
Transferring other groups
BRITE hierarchy
Sysname
(3S)-2,3-epoxy-2,3-dihydrosqualene mutase (cyclizing, achilleol-B-forming)
Reaction(IUBMB)
(3S)-2,3-epoxy-2,3-dihydrosqualene = achilleol B [RN:R09908]
Reaction(KEGG)
Substrate
(3S)-2,3-epoxy-2,3-dihydrosqualene [CPD:C01054]
Product
achilleol B [CPD:C20187]
Comment
Achilleol B is probably formed by cleavage of the 8-14 and 9-10 bonds of (3S)-2,3-epoxy-2,3-dihydrosqualene as part of the cyclization reaction, after formation of the oleanane skeleton.
Reference
1  [PMID:21526825]
  Authors
Ito R, Mori K, Hashimoto I, Nakano C, Sato T, Hoshino T
  Title
Triterpene cyclases from Oryza sativa L.: cycloartenol, parkeol and achilleol B synthases.
  Journal
Org. Lett. 13 (2011) 2678-81.
Other DBs
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