| Entry |
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| Name |
marneral synthase
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| Class |
Isomerases;
Intramolecular transferases;
Transferring other groups
 |
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| Sysname |
(3S)-2,3-epoxy-2,3-dihydrosqualene mutase (cyclizing, marneral-forming)
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| Reaction(IUBMB) |
(3S)-2,3-epoxy-2,3-dihydrosqualene = marneral [RN: R09913]
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| Reaction(KEGG) |
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| Substrate |
(3S)-2,3-epoxy-2,3-dihydrosqualene [CPD: C01054]
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| Product |
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| Comment |
Marneral is a triterpenoid formed by Grob fragmentation of the A ring of 2,3-epoxy-2,3-dihydrosqualene during cyclization.
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| Pathway |
| Sesquiterpenoid and triterpenoid biosynthesis | | Biosynthesis of secondary metabolites |
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| Orthology |
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| Genes |
 |
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| Reference |
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| Authors |
Xiong Q, Wilson WK, Matsuda SP |
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| Title |
An Arabidopsis oxidosqualene cyclase catalyzes iridal skeleton formation by Grob fragmentation. |
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| Journal |
Angew. Chem. Int. Ed. Engl. 45 (2006) 1285-8. |
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| Other DBs |
ExplorEnz - The Enzyme Database: IUBMB Enzyme Nomenclature: ExPASy - ENZYME nomenclature database: BRENDA, the Enzyme Database: |
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