| Entry |
|
|---|
| Name |
pyridoxal 5'-phosphate synthase;
pyridoxamine 5'-phosphate oxidase;
pyridoxamine phosphate oxidase;
pyridoxine (pyridoxamine)phosphate oxidase;
pyridoxine (pyridoxamine) 5'-phosphate oxidase;
pyridoxaminephosphate oxidase (EC 1.4.3.5: deaminating);
PMP oxidase;
pyridoxol-5'-phosphate:oxygen oxidoreductase (deaminating)
(incorrect);
pyridoxamine-phosphate oxidase;
PdxH |
|---|
| Class |
Oxidoreductases;
Acting on the CH-NH2 group of donors;
With oxygen as acceptor
 |
|---|
| Sysname |
pyridoxamine-5'-phosphate:oxygen oxidoreductase (deaminating) |
|---|
| Reaction(IUBMB) |
(1) pyridoxamine 5'-phosphate + H2O + O2 = pyridoxal 5'-phosphate +
NH3 + H2O2 [RN:R00277];
(2) pyridoxine 5'-phosphate + O2 = pyridoxal 5'-phosphate + H2O2
[RN:R00278] |
|---|
| Reaction(KEGG) |
R00277 R00278;
(other) R01710 R01711 R06133
 |
|---|
| Substrate |
pyridoxamine 5'-phosphate [CPD:C00647];
H2O [CPD:C00001];
O2 [CPD:C00007];
pyridoxine 5'-phosphate [CPD:C00627] |
|---|
| Product |
pyridoxal 5'-phosphate [CPD:C00018];
NH3 [CPD:C00014];
H2O2 [CPD:C00027] |
|---|
| Cofactor |
FMN [CPD:C00061] |
|---|
| Comment |
A flavoprotein (FMN). In Escherichia coli, the coenzyme pyridoxal
5'-phosphate is synthesized de novo by a pathway that involves EC
1.2.1.72 (erythrose-4-phosphate dehydrogenase), EC 1.1.1.290
(4-phosphoerythronate dehydrogenase), EC 2.6.1.52 (phosphoserine
transaminase), EC 1.1.1.262 (4-hydroxythreonine-4-phosphate
dehydrogenase), EC 2.6.99.2 (pyridoxine 5'-phosphate synthase) and
EC 1.4.3.5 (with pyridoxine 5'-phosphate as substrate).
N4'-Substituted pyridoxamine derivatives are also oxidized in
reaction (1) to form pyridoxal 5'-phosphate and the corresponding
primary amine. |
|---|
| Pathway |
PATH: ec00750 Vitamin B6 metabolism
PATH: ec01100 Metabolic pathways |
|---|
| Orthology |
KO: K00275 pyridoxamine 5'-phosphate oxidase |
|---|
| Genes |
HSA: 55163(PNPO)
PTR: 749248(PNPO)
MCC: 694949(PNPO)
MMU: 103711(Pnpo)
RNO: 64533(Pnpo)
CFA: 480540(PNPO)
BTA: 512573(PNPO)
ECB: 100055489
XLA: 444757
DRE: 402868(pnpo)
BFO: BRAFLDRAFT_126490
CIN: 100180124 100184029
SPU: 579975
DME: Dmel_CG31472 Dmel_CG31473
DPO: Dpse_GA27512
DAN: Dana_GF16863 Dana_GF18174
DER: Dere_GG14208 Dere_GG14219
DPE: Dper_GL12458
DSE: Dsec_GM10975 Dsec_GM10976
DSI: Dsim_GD19951 Dsim_GD19952
DYA: Dyak_GE11187 Dyak_GE11188 Dyak_GE24943
DGR: Dgri_GH18971 Dgri_GH18972
DMO: Dmoj_GI24131 Dmoj_GI24132
AGA: AgaP_AGAP002227
AAG: AaeL_AAEL002703
CQU: CpipJ_CPIJ011877
AME: 409066
TCA: 660386
API: 100159909
CEL: F57B9.1
CBR: CBG16488
BMY: Bm1_26535
SMM: Smp_051550.2
NVE: NEMVE_v1g231487 NEMVE_v1g80869
HMG: 100202407
TAD: TRIADDRAFT_53373
SCE: YBR035C(PDX3)
AGO: AGOS_AAR186W
KLA: KLLA0B07062g
LTH: KLTH0C08272g
DHA: DEHA0F18491g
PIC: PICST_50793(PDX3)
PPA: PAS_chr1-1_0448
VPO: Kpol_1053p6
ZRO: ZYRO0A03740g
CTP: CTRG_00420
CDU: CD36_29950
CGR: CAGL0I04708g
YLI: YALI0D14322g
SPO: SPAC1093.02
NCR: NCU08269
PAN: PODANSg7151
MGR: MGG_01535
FGR: FG09639.1 FG11500.1
AFM: AFUA_5G10650
AOR: AO090010000473 AO090023000033
ANG: An14g04050
AFV: AFLA_104650 AFLA_119560
PCS: Pc21g10250
NFI: NFIA_076560
CIM: CIMG_00702
URE: UREG_00694
SSL: SS1G_13739
BFU: BC1G_10096
DDI: DDB_0231657
ECO: b1638(pdxH)
ECJ: JW1630(pdxH)
ECD: ECDH10B_1772(pdxH)
EBW: BWG_1453(pdxH)
ECE: Z2652(pdxH)
ECS: ECs2347
ECF: ECH74115_2350(pdxH)
ETW: ECSP_2203(pdxH)
ECG: E2348C_1725(pdxH)
ECC: c2030(pdxH)
ECI: UTI89_C1829(pdxH)
ECP: ECP_1584
ECV: APECO1_721(pdxH)
ECW: EcE24377A_1848(pdxH)
ECX: EcHS_A1714(pdxH)
ECM: EcSMS35_1561(pdxH)
ECY: ECSE_1761
ECL: EcolC_1991
ECK: EC55989_1806(pdxH)
ECQ: ECED1_1839(pdxH)
ECR: ECIAI1_1690(pdxH)
ECT: ECIAI39_1417(pdxH)
ECZ: ECS88_1686(pdxH)
EUM: ECUMN_1929(pdxH)
ELF: LF82_1607(pdxH)
EBL: B21_01598(pdxH)
EBD: ECBD_2005
EBR: ECB_01608(pdxH)
EOH: ECO103_1779(pdxH)
EOI: ECO111_2108(pdxH)
EOJ: ECO26_2367(pdxH)
EFE: EFER_1405(pdxH)
STY: STY1674(pdxH)
STT: t1316(pdxH)
SPT: SPA1405(pdxH)
SEK: SSPA1305
SPQ: SPAB_01873
SEI: SPC_2283(pdxH)
SEC: SC1466(pdxH)
SEH: SeHA_C1618(pdxH)
SEE: SNSL254_A1558(pdxH)
SEW: SeSA_A1545(pdxH)
SEA: SeAg_B1726(pdxH)
SED: SeD_A1895(pdxH)
SEG: SG1670(pdxH)
SET: SEN1599(pdxH)
SES: SARI_01534
STM: STM1448(pdxH)
YPE: YPO2370(pdxH)
YPK: y1965(pdxH)
YPM: YP_2156(pdxH)
YPA: YPA_1716
YPN: YPN_1827
YPG: YpAngola_A2555(pdxH)
YPP: YPDSF_0776
YPS: YPTB2284(pdxH)
YPI: YpsIP31758_1772(pdxH)
YPY: YPK_1880
YPB: YPTS_2361
YEN: YE2140(pdxH)
SFL: SF1663(pdxH)
SFX: S1795(pdxH)
SFV: SFV_1655(pdxH)
SSN: SSON_1518(pdxH)
SBO: SBO_1496(pdxH)
SBC: SbBS512_E1830(pdxH)
SDY: SDY_1861(pdxH)
ECA: ECA1935(pdxH)
PCT: PC1_2378
PWA: Pecwa_2662
ETA: ETA_17880(pdxH)
PLU: plu2597(pdxH)
PAY: PAU_01937(pdxH)
WBR: WGLp337(pdxH)
SGL: SG1447
ENT: Ent638_1810
ESA: ESA_01997
CTU: Ctu_19960(pdxH)
KPN: KPN_01976(pdxH)
KPE: KPK_2372(pdxH)
KPU: KP1_3048(pdxH)
CKO: CKO_01650
SPE: Spro_2218
PMR: PMI1387(pdxH)
EIC: NT01EI_2097
ETR: ETAE_1689(pdxH)
BFL: Bfl370(pdxH)
BPN: BPEN_381(pdxH)
HDE: HDEF_0670(pdxH)
DDA: Dd703_1693
DDC: Dd586_1677
DZE: Dd1591_1726
HIN: HI0863(pdxH)
HIT: NTHI1032(pdxH)
HIP: CGSHiEE_07725
HIQ: CGSHiGG_07835
HDU: HD0214(pdxH)
MSU: MS2064(pdxH)
APL: APL_2009(pdxH)
APJ: APJL_2059(pdxH)
APA: APP7_2096
ASU: Asuc_0247
AAP: NT05HA_1671
AAT: D11S_0172
XFA: XF1337
XFT: PD0583(pdxH)
XFM: Xfasm12_0693
XFN: XfasM23_0612
XCC: XCC2840(pdxH)
XCB: XC_1267 XC_1270
XCA: xccb100_1316
XCV: XCV3159(pdxH)
XAC: XAC3009(pdxH)
XOO: XOO1245(pdxH)
XOM: XOO_1145
XOP: PXO_02183
SML: Smlt3616(pdxH)
SMT: Smal_3033
VCH: VCA1079
VCO: VC0395_0163(pdxH)
VCM: VCM66_A1037(pdxH)
VCJ: VCD_000263
VVU: VV2_1122
VVY: VVA1648
VPA: VPA1730
VHA: VIBHAR_07092
VSP: VS_II0011
VEX: VEA_001014
VFI: VF_A1161(pdxH)
VFM: VFMJ11_A1255(pdxH)
VSA: VSAL_II0021(pdxH)
PPR: PBPRB2015
PAE: PA1049(pdxH)
PAU: PA14_50800(pdxH)
PAP: PSPA7_4331(pdxH)
PAG: PLES_42741(pdxH)
PPU: PP_1129(pdxH)
PPF: Pput_1165
PPG: PputGB1_4286
PPW: PputW619_1150
PST: PSPTO_4116(pdxH)
PSB: Psyr_3853
PSP: PSPPH_1409(pdxH)
PFL: PFL_1283(pdxH)
PFO: Pfl01_1229
PFS: PFLU1328(pdxH)
PEN: PSEEN1277
PMY: Pmen_1436
PSA: PST_1526(pdxH)
CJA: CJA_1341(pdxH)
AVN: Avin_19500(pdxH)
PAR: Psyc_1358(pdxH)
PCR: Pcryo_1007
PRW: PsycPRwf_1259
ACI: ACIAD3501(pdxH)
ACB: A1S_3319
ABM: ABSDF3447(pdxH)
ABY: ABAYE0168(pdxH)
ABC: ACICU_03516
ABN: AB57_3768(pdxH)
SON: SO_2895(pdxH)
SDN: Sden_1170 Sden_2277
SFR: Sfri_1702
SAZ: Sama_1961
SBL: Sbal_1770
SBM: Shew185_1763
SBN: Sbal195_1807
SBP: Sbal223_2515
SLO: Shew_1622
SPC: Sputcn32_1649
SSE: Ssed_2606
SPL: Spea_2477
SHE: Shewmr4_1559
SHM: Shewmr7_1634
SHN: Shewana3_1626
SHW: Sputw3181_2377
SHL: Shal_1806
SWD: Swoo_2060
SWP: swp_3021
ILO: IL1209(pdxH)
CPS: CPS_1053(pdxH)
PHA: PSHAa0658(pdxH)
PAT: Patl_3147
SDE: Sde_2258
MAQ: Maqu_0155
AMC: MADE_02996
PIN: Ping_1481
TTU: TERTU_2874(pdxH)
CBU: CBU_0928(pdxH)
CBS: COXBURSA331_A1016(pdxH)
CBD: CBUD_1146(pdxH)
CBG: CbuG_1077(pdxH)
CBC: CbuK_0909(pdxH)
LPN: lpg0536(pdxH) lpg2139
LPF: lpl0582(pdxH) lpl2068
LPP: lpp0601(pdxH) lpp2078
LPC: LPC_1588(pdxH) LPC_2766(pdxH)
TCX: Tcr_0363 Tcr_1992
AEH: Mlg_1988
HHA: Hhal_1782
HNA: Hneap_2153
HCH: HCH_04530(pdxH)
CSA: Csal_1900
ABO: ABO_0302(pdxH)
MMW: Mmwyl1_2993
AHA: AHA_1408(pdxH)
ASA: ASA_1380(pdxH)
TAU: Tola_0601
DNO: DNO_1023(pdxH)
AFE: Lferr_0778
AFR: AFE_0628(pdxH)
BCI: BCI_0082(pdxH)
RMA: Rmag_0434
VOK: COSY_0404(pdxH)
NMA: NMA1572(pdxH)
NME: NMB1360(pdxH)
NMC: NMC1295(pdxH)
NMN: NMCC_1271(pdxH)
NMI: NMO_1196(pdxH)
NGO: NGO0658
NGK: NGK_1250
CVI: CV_0059(pdxH)
LHK: LHK_02017(pdxH)
RSO: RSc0767(pdxH1) RSp0678(pdxH2)
RPI: Rpic_0717
RPF: Rpic12D_0787
REU: Reut_A0815
REH: H16_A2802(pdxH)
RME: Rmet_2642
CTI: RALTA_A2292(pdxH)
BMA: BMA0359(pdxH)
BMV: BMASAVP1_A0659(pdxH)
BML: BMA10229_A2494(pdxH)
BMN: BMA10247_0107(pdxH)
BPS: BPSL0854(pdxH)
BPM: BURPS1710b_1061(pdxH)
BPL: BURPS1106A_0904(pdxH)
BPD: BURPS668_0901(pdxH)
BPR: GBP346_A0828(pdxH)
BTE: BTH_I0717(pdxH)
BVI: Bcep1808_2662
BUR: Bcep18194_A5900 Bcep18194_B1572
BCN: Bcen_1957
BCH: Bcen2424_2568
BCM: Bcenmc03_2592
BCJ: BCAL2782(pdxH)
BAM: Bamb_2616
BAC: BamMC406_2487
BMU: Bmul_0728
BMJ: BMULJ_02532(pdxH)
BXE: Bxe_A0741
BPH: Bphy_0514
BPY: Bphyt_3221
BGL: bglu_1g29320 bglu_2g09280
PNU: Pnuc_0663
PNE: Pnec_1193
BPE: BP3251(pdxH)
BPA: BPP3607(pdxH)
BBR: BB4042(pdxH)
BPT: Bpet0860(pdxH)
BAV: BAV2823(pdxH)
RFR: Rfer_2059
POL: Bpro_3559
PNA: Pnap_2989
AAV: Aave_2803
AJS: Ajs_2058
VEI: Veis_2564
DAC: Daci_3944
DIA: Dtpsy_1881
VAP: Vapar_3713
CTT: CtCNB1_2290 CtCNB1_2566
MPT: Mpe_A2931
HAR: HEAR2598(pdxH)
MMS: mma_2836(pdxH)
LCH: Lcho_2922
APP: CAP2UW1_1090
ABU: Abu_1541(pdxH)
GEO: Geob_1162
BBA: Bd2568(pdxH)
ADE: Adeh_1455
ACP: A2cp1_2494
AFW: Anae109_1699
ANK: AnaeK_2407
MXA: MXAN_1295(pdxH)
SCL: sce5083(pdxH)
HOH: Hoch_3489
WOL: WD1159(pdxH)
WRI: WRi_011340(pdxH)
WPI: WPa_0881(pdxH)
AMA: AM281(pdxH)
AMF: AMF_207(pdxH)
ACN: ACIS_01013(pdhX)
APH: APH_1008(pdxH)
ERU: Erum1850(pdxH)
ERW: ERWE_CDS_01840(pdxH)
ERG: ERGA_CDS_01790(pdxH)
ECN: Ecaj_0183
ECH: ECH_0931(pdxH)
NSE: NSE_0371
NRI: NRI_0355
PUB: SAR11_0613(pdxH)
MLO: mll7454
MES: Meso_0724
PLA: Plav_0790
SME: SMc00069(pdxH)
SMD: Smed_0509
ATU: Atu0760(pdxH)
ATC: AGR_C_1381
ARA: Arad_1220(pdxH)
AVI: Avi_1026(pdxH)
RET: RHE_CH00941(pdxH)
REC: RHECIAT_CH0001038(pdxH)
RLE: RL1014(pdxH)
RLT: Rleg2_0594
RLG: Rleg_0634
RHI: NGR_c05140(pdxH)
LAS: CLIBASIA_05360(pdxH)
BME: BMEI1517
BMF: BAB1_0444(pdxH)
BMB: BruAb1_0439(pdxH)
BMC: BAbS19_I04090
BMS: BR0416(pdxH)
BMT: BSUIS_A0442(pdxH)
BOV: BOV_0424(pdxH)
BCS: BCAN_A0421(pdxH)
BMR: BMI_I420(pdxH)
OAN: Oant_0531
BJA: bll2624(pdxH)
BRA: BRADO2146(pdxH)
BBT: BBta_2463(pdxH)
RPA: RPA1196(pdxH)
RPB: RPB_1205
RPC: RPC_1136
RPD: RPD_1307
RPE: RPE_4594
RPT: Rpal_1389
NWI: Nwi_0622
NHA: Nham_0765
OCA: OCAR_6910(pdxH)
BHE: BH04290(pdxH)
BQU: BQ03480(pdxH)
BBK: BARBAKC583_0394(pdxH)
BTR: Btr_0642(pdxH)
BGR: Bgr_04610(pdxH)
XAU: Xaut_2478
AZC: AZC_1197
MEX: Mext_4295
MEA: Mex_1p4692(pdxH)
MDI: METDI5298(pdxH)
MRD: Mrad2831_3947
MET: M446_2100
MPO: Mpop_4813
MCH: Mchl_4664
MNO: Mnod_1068
BID: Bind_1108
MSL: Msil_1088
CCR: CC_0918
CCS: CCNA_00966
CAK: Caul_1311
PZU: PHZ_c2738(pdxH)
SIL: SPO2141
SIT: TM1040_1148
RSP: RSP_2345(pdxH)
RSH: Rsph17029_1020
RSQ: Rsph17025_1052
RSK: RSKD131_0671
JAN: Jann_2475
RDE: RD1_3198(pdxH)
PDE: Pden_0858 Pden_4662
DSH: Dshi_1789(pdxH)
MMR: Mmar10_0857
HNE: HNE_0824(pdxH)
HBA: Hbal_1195
ZMO: ZMO0851
ZMN: Za10_0440
NAR: Saro_0048
SAL: Sala_0654
SWI: Swit_4754
ELI: ELI_13435
GOX: GOX1988
GBE: GbCGDNIH1_0226
ACR: Acry_0829
GDI: GDI_3232(pdxH)
GDJ: Gdia_3130
APT: APA01_11510
RRU: Rru_A2627
RCE: RC1_0584(pdxH)
MAG: amb0886
MTU: Rv2607(pdxH)
MTC: MT2682(pdxH)
MRA: MRA_2635(pdxH)
MTF: TBFG_12626
MTB: TBMG_01364(TBMG_01364.1)
MBO: Mb2639(pdxH)
MBB: BCG_2632(pdxH)
MBT: JTY_2626(pdxH)
MLE: ML2131(pdxH)
MLB: MLBr_02131(pdxH)
MPA: MAP0828(pdxH)
MAV: MAV_1017(pdxH)
MSM: MSMEG_5675(pdxH)
MUL: MUL_0257(pdxH)
MVA: Mvan_5024
MGI: Mflv_1727
MAB: MAB_0933 MAB_3823
MMC: Mmcs_4458
MKM: Mkms_4545
MJL: Mjls_4840
MMI: MMAR_4642(pdxH)
NFA: nfa6600
RHA: RHA1_ro04994(pdxH) RHA1_ro05689
RER: RER_43310 RER_46150(pdxH) pREL1_0298(phzG)
ROP: ROP_50550(pdxH) ROP_57490
GBR: Gbro_1263
SCO: SCO4387(SCD10.19c) SCO4418(SC6F11.16c)
SMA: SAV_3824(pdxH2) SAV_3858(pdxH1)
SGR: SGR_3026 SGR_3075
CMI: CMM_1140 CMM_2909
CMS: CMS_1464
ART: Arth_1504
ACH: Achl_1505
RSA: RSal33209_0785
BCV: Bcav_0497 Bcav_3790
BFA: Bfae_30330
KSE: Ksed_05820 Ksed_24050
NCA: Noca_0734
TFU: Tfu_0248
TCU: Tcur_0835
SRO: Sros_1006
FRA: Francci3_0079
FRE: Franean1_7230
FAL: FRAAL0106(pdxH)
ACE: Acel_0116
NML: Namu_4707
KRA: Krad_1798 Krad_3597
SEN: SACE_0641(pdxH)
SVI: Svir_33810
AMI: Amir_0501
STP: Strop_0424
SAQ: Sare_0512
CAI: Caci_8786
RXY: Rxyl_2372
LIL: LA1166(pdxH)
LIC: LIC12520(pdxH)
LBJ: LBJ_2141(pdxH)
LBL: LBL_2135(pdxH)
LBI: LEPBI_I1407(pdxH)
LBF: LBF_1353(pdxH)
BTH: BT_1577
BFR: BF1453
BFS: BF1385(pdxH)
PGI: PG1714(pdxH)
PGN: PGN_0403
PDI: BDI_2095
SRU: SRU_0544(pdxH)
RMR: Rmar_0186
CHU: CHU_1775(pdxH)
DFE: Dfer_0555
CPI: Cpin_0886
PHE: Phep_1895
GFO: GFO_1835(pdxH)
FJO: Fjoh_4542
FPS: FP1704(pdxH)
FBA: FIC_00705
COC: Coch_0417
RBI: RB2501_12784
BBL: BLBBGE_050(ppk)
BPI: BPLAN_583(pdxH)
OTE: Oter_0848 Oter_0885
MIN: Minf_1150(pdxH)
AMU: Amuc_1262
GAU: GAU_2845(pdxH)
RBA: RB10006(pdxH)
SYN: sll1440(pdxH)
SYX: SynWH7803_0817
SYP: SYNPCC7002_A2591(pdxH)
TEL: tll0331(pdxH)
MAR: MAE_57790(pdxH)
CYT: cce_0797(pdxH)
CYP: PCC8801_0930
CYC: PCC7424_1509
CYN: Cyan7425_1243
CYH: Cyan8802_0957
ANA: all1248
NPU: Npun_F6283
AVA: Ava_0557
PMT: PMT2199(pdxH)
PMF: P9303_29241(pdxH)
AMR: AM1_4597(pdxH)
CTS: Ctha_0608
RRS: RoseRS_0423
RCA: Rcas_1067
CAG: Cagg_0332
TRO: trd_A0007(pdxH)
STI: Sthe_2419
DRA: DR_0495
DGE: Dgeo_0443
DDR: Deide_06601
TTR: Tter_0835
 |
|---|
| Structures |
PDB: 1CI0 1DNL 1G76 1G77 1G78 1G79 1JNW 1WV4 2A2J 2HHZ
3HY8 |
|---|
Reference
Authors
Title
Journal
Organism
|
1 [PMID:6822512]
Choi JD, Bowers-Komro M, Davis MD, Edmondson DE, McCormick DB.
Kinetic properties of pyridoxamine (pyridoxine)-5'-phosphate oxidase
from rabbit liver.
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Escherichia coli [GN:eco] |
|---|
| Other DBs |
ExplorEnz - The Enzyme Database: 1.4.3.5
IUBMB Enzyme Nomenclature: 1.4.3.5
ExPASy - ENZYME nomenclature database: 1.4.3.5
BRENDA, the Enzyme Database: 1.4.3.5
CAS: 9029-21-4 |
|---|
