KEGG   ENZYME: 2.4.1.116Help
Entry
EC 2.4.1.116                Enzyme                                 

Name
cyanidin 3-O-rutinoside 5-O-glucosyltransferase;
uridine diphosphoglucose-cyanidin 3-rhamnosylglucoside 5-O-glucosyltransferase;
cyanidin-3-rhamnosylglucoside 5-O-glucosyltransferase;
UDP-glucose:cyanidin-3-O-D-rhamnosyl-1,6-D-glucoside 5-O-D-glucosyltransferase
Class
Transferases;
Glycosyltransferases;
Hexosyltransferases
BRITE hierarchy
Sysname
UDP-alpha-D-glucose:cyanidin-3-O-alpha-L-rhamnosyl-(1->6)-beta-D-glucoside 5-O-beta-D-glucosyltransferase
Reaction(IUBMB)
UDP-alpha-D-glucose + cyanidin-3-O-rutinoside = UDP + cyanidin 3-O-rutinoside 5-O-beta-D-glucoside [RN:R06819]
Reaction(KEGG)
R06819;
(other) R06803
Show
Substrate
UDP-alpha-D-glucose [CPD:C00029];
cyanidin-3-O-rutinoside
Product
UDP [CPD:C00015];
cyanidin 3-O-rutinoside 5-O-beta-D-glucoside [CPD:C12646]
Comment
Isolated from the plants Silene dioica (red campion) [1], Iris ensata (Japanese iris) [2] and Iris hollandica (Dutch iris) [3]. Also acts on the 3-O-rutinosides of pelargonidin, delphinidin and malvidin, but not the corresponding glucosides or 6-acylglucosides. The enzyme does not catalyse the glucosylation of the 5-hydroxy group of cyanidin 3-glucoside.
History
EC 2.4.1.116 created 1984 (EC 2.4.1.235 created 2004, incorporated 2006), modified 2006, modified 2013
Pathway
Anthocyanin biosynthesis
Reference
1  [PMID:751641]
  Authors
Kamsteeg J, van Brederode J, van Nigtevecht G.
  Title
Identification, properties, and genetic control of UDP-glucose: cyanidin-3-rhamnosyl-(1 leads to 6)-glucoside-5-O-glucosyltransferase isolated from petals of the red campion (Silene dioica).
  Journal
Biochem. Genet. 16 (1978) 1059-71.
  Organism
Silene dioica
Reference
2
  Authors
Yabuya, T., Yamaguchi, M., Imayama, T., Katoh, K. and Ino I.
  Title
Anthocyanin 5-O-glucosyltransferase in flowers of Iris ensata.
  Journal
Plant Sci. 162 (2002) 779-784.
Reference
3
  Authors
Imayama, T., Yoshihara, Y., Fukuchi-Mizutani, M., Tanaka, Y., Ino, I. and Yabuya, T.
  Title
Isolation and characterization of a cDNA clone of UDP-glucose:anthocyanin 5-O-glucosyltransferase in Iris hollandica.
  Journal
Plant Sci. 167 (2004) 1243-1248.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 
CAS: 
70248-66-7

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