KEGG   ENZYME: 4.2.3.31Help
Entry
EC 4.2.3.31                 Enzyme                                 

Name
ent-pimara-9(11),15-diene synthase;
PMD synthase
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
BRITE hierarchy
Sysname
ent-copalyl-diphosphate diphosphate-lyase [ent-pimara-9(11),15-diene-forming]
Reaction(IUBMB)
ent-copalyl diphosphate = ent-pimara-9(11),15-diene + diphosphate [RN:R09681]
Reaction(KEGG)
Substrate
ent-copalyl diphosphate [CPD:C06089]
Product
ent-pimara-9(11),15-diene [CPD:C19810];
diphosphate [CPD:C00013]
Comment
This enzyme is involved in the biosynthesis of the diterpenoid viguiepinol and requires Mg2+, Co2+, Zn2+ or Ni2+ for activity.
History
EC 4.2.3.31 created 2008
Reference
1  [PMID:17148547]
  Authors
Ikeda C, Hayashi Y, Itoh N, Seto H, Dairi T.
  Title
Functional analysis of eubacterial ent-copalyl diphosphate synthase and pimara-9(11),15-diene synthase with unique primary sequences.
  Journal
J. Biochem. 141 (2007) 37-45.
  Organism
Streptomyces sp.
Other DBs
ExplorEnz - The Enzyme Database: 
IUBMB Enzyme Nomenclature: 
ExPASy - ENZYME nomenclature database: 
BRENDA, the Enzyme Database: 

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