| Entry |
|
|---|
| Name |
allene-oxide cyclase |
|---|
| Class |
Isomerases;
Intramolecular oxidoreductases;
Other intramolecular oxidoreductases
 |
|---|
| Sysname |
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate isomerase
(cyclizing) |
|---|
| Reaction(IUBMB) |
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate =
(15Z)-12-oxophyto-10,15-dienoate [RN:R03402] |
|---|
| Reaction(KEGG) |
R03402
 |
|---|
| Substrate |
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate [CPD:C04672] |
|---|
| Product |
(15Z)-12-oxophyto-10,15-dienoate [CPD:C01226] |
|---|
| Comment |
Allene oxides formed by the action of EC 4.2.1.92 hydroperoxide
dehydratase, are converted into cyclopentenone derivatives. |
|---|
| Pathway |
ec00592 alpha-Linolenic acid metabolism
ec01100 Metabolic pathways |
|---|
| Orthology |
K10525 allene oxide cyclase |
|---|
| Genes |
ATH: AT1G13280(AOC4) AT3G25760(AOC1) AT3G25770(AOC2) AT3G25780(AOC3)
OSA: 4333201(Os03g0438100)
 |
|---|
Reference
Authors
Title
Journal
Organism
|
1 [PMID:3178850]
Hamberg M.
Biosynthesis of 12-oxo-10,15(Z)-phytodienoic acid: identification of
an allene oxide cyclase.
Biochem. Biophys. Res. Commun. 156 (1988) 543-50.
Zea mays [GN:zma] |
|---|
| Other DBs |
ExplorEnz - The Enzyme Database: 5.3.99.6
IUBMB Enzyme Nomenclature: 5.3.99.6
ExPASy - ENZYME nomenclature database: 5.3.99.6
BRENDA, the Enzyme Database: 5.3.99.6
CAS: 118390-59-3 |
|---|
