KEGG   GLYCAN: G13115Help
Entry
G13115                      Glycan                                 

Name
Mannose-capped lipoarabinomannan;
ManLAM
Composition
(Araf)17 (Man)13 (R)2 (Ino-P)1
Structure
KCF fileKCaMSNFG
Comment
R, fatty acyl group
Pathway
map00571  Lipoarabinomannan (LAM) biosynthesis
map01100  Metabolic pathways
map04625  C-type lectin receptor signaling pathway
map05152  Tuberculosis
Reference
1  [PMID:12765785]
  Authors
Nigou J, Gilleron M, Puzo G.
  Title
Lipoarabinomannans: from structure to biosynthesis.
  Journal
Biochimie 85:153-66 (2003)
DOI:10.1016/S0300-9084(03)00048-8
Reference
2  [PMID:29443974]
  Authors
Angala SK, Palcekova Z, Belardinelli JM, Jackson M.
  Title
Covalent modifications of polysaccharides in mycobacteria.
  Journal
Nat Chem Biol 14:193-198 (2018)
DOI:10.1038/nchembio.2571
KCF data Show

NODE        33
            1   Ino-P    72.9  13.8
            2   Man      66.3     8
            3   R        66.2  18.2
            4   Man      62.9  13.8
            5   R        59.1     8
            6   Man      52.9  13.8
            7   Man      42.9  13.8
            8   Man        33  13.8
            9   Man        31  20.1
            10  Man      22.8  13.8
            11  Araf     22.8   8.3
            12  Araf     14.4   1.3
            13  Araf      6.7  -5.1
            14  Araf     -2.2 -11.8
            15  Araf     -3.7  -5.1
            16  Araf    -12.1 -19.2
            17  Araf    -12.2 -11.8
            18  Araf      -14  -5.1
            19  Araf    -22.1 -11.8
            20  Araf    -23.5  -5.1
            21  Araf    -31.4  -9.1
            22  Araf    -31.7  -0.9
            23  Araf    -31.7 -11.8
            24  Araf    -41.4  -9.1
            25  Araf    -41.5  -0.9
            26  Araf    -41.6 -11.8
            27  Man     -51.6  -9.1
            28  Man     -51.9  -0.9
            29  Araf    -51.9 -11.8
            30  Man     -60.9  -0.9
            31  Man     -61.6 -11.8
            32  Man     -62.1  -9.1
            33  Man     -72.1 -11.8
EDGE        32
            1     2:a1    1:2  
            2     3       1:3  
            3     4:a1    1:6  
            4     5       2:6  
            5     6:a1    4:6  
            6     7:a1    6:6  
            7     8:a1    7:6  
            8     9:a1    8:2  
            9    10:a1    8:6  
            10   11      10    
            11   12:a1   11:5  
            12   13:a1   12:5  
            13   14:a1   13:5  
            14   15:a1   13:3  
            15   16:b1   14:2  
            16   17:a1   14:3  
            17   18:a1   15:5  
            18   19:a1   17:5  
            19   20:a1   18:5  
            20   23:a1   19:5  
            21   21:a1   20:3  
            22   22:a1   20:5  
            23   24:b1   21:2  
            24   25:b1   22:2  
            25   26:a1   23:5  
            26   27:a1   24:2  
            27   28:a1   25:5  
            28   29:b1   26:2  
            29   32:a1   27:2  
            30   30:a1   28:2  
            31   31:a1   29:2  
            32   33:a1   31:2
BRACKET     1  -6.2  -4.2  -6.2  -6.0
            1  -0.8  -6.0  -0.8  -4.2
            1 w
            2 -14.8 -10.6 -14.8 -12.8
            2  -9.0 -12.7  -9.0 -10.5
            2 v
            3  40.4  15.6  40.4  12.2
            3  46.8  12.1  46.8  15.5
            3 n
            4  30.6  15.4  30.6  11.8
            4  36.7  11.8  36.7  15.4
            4 m
            5   4.0  -6.0   4.0  -8.2
            5   9.7  -3.5   9.7  -1.5
            5 p
            6  12.0   1.0  12.0  -1.9
            6  17.4   2.6  17.4   5.5
            6 o
            7  -5.0 -12.6  -5.0 -15.0
            7   0.9 -10.7   0.9  -8.3
            7 q
            8  -6.5 -13.7  -6.5 -16.5
            8  18.5   4.1  18.5   6.9
            8 r
            9  29.3  16.2  29.3  11.0
            9  48.2  10.9  48.2  16.1
            9 l
            10 -62.1   1.0 -62.1  -2.4
            10 -57.6  -2.4 -57.6   1.0
            10 0-2
            11 -63.4  -7.1 -63.4 -10.5
            11 -58.9 -10.5 -58.9  -7.1
            11 0-2
            12 -73.4 -10.1 -73.4 -13.5
            12 -68.9 -13.5 -68.9 -10.1
            12 0-2

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