KEGG   GLYCAN: G13116Help
Entry
G13116                      Glycan                                 

Name
Phospho-myo-inositol-capped LAM;
PILAM
Composition
(Araf)17 (Man)7 (R)2 (Ino-P)4
Structure
KCF fileKCaMSNFG
Comment
R, fatty acyl group
Pathway
map00571  Lipoarabinomannan (LAM) biosynthesis
map01100  Metabolic pathways
Reference
1  [PMID:12765785]
  Authors
Nigou J, Gilleron M, Puzo G.
  Title
Lipoarabinomannans: from structure to biosynthesis.
  Journal
Biochimie 85:153-66 (2003)
DOI:10.1016/S0300-9084(03)00048-8
Reference
2  [PMID:29443974]
  Authors
Angala SK, Palcekova Z, Belardinelli JM, Jackson M.
  Title
Covalent modifications of polysaccharides in mycobacteria.
  Journal
Nat Chem Biol 14:193-198 (2018)
DOI:10.1038/nchembio.2571
KCF data Show

NODE        30
            1   Ino-P    67.2  13.5
            2   Man      60.6   7.7
            3   R        60.5  17.9
            4   Man      57.2  13.5
            5   R        53.4   7.7
            6   Man      47.2  13.5
            7   Man      37.2  13.5
            8   Man      27.3  13.5
            9   Man      25.3  19.8
            10  Man      17.1  13.5
            11  Araf     17.1     8
            12  Araf      8.7     1
            13  Araf        1  -5.4
            14  Araf     -7.9 -12.1
            15  Araf     -9.4  -5.4
            16  Araf    -17.8 -19.5
            17  Araf    -17.9 -12.1
            18  Araf    -19.7  -5.4
            19  Araf    -27.8 -12.1
            20  Araf    -29.2  -5.4
            21  Araf    -37.1  -9.4
            22  Araf    -37.4  -1.2
            23  Araf    -37.5 -12.1
            24  Araf    -47.1  -9.4
            25  Araf    -47.2  -1.2
            26  Araf    -47.2 -12.1
            27  Ino-P   -56.8  -1.2
            28  Ino-P   -56.8  -9.4
            29  Araf    -57.7 -12.1
            30  Ino-P   -67.4 -12.1
EDGE        29
            1     2:a1    1:2  
            2     3       1:3  
            3     4:a1    1:6  
            4     5       2:6  
            5     6:a1    4:6  
            6     7:a1    6:6  
            7     8:a1    7:6  
            8     9:a1    8:2  
            9    10:a1    8:6  
            10   11      10    
            11   12:a1   11:5  
            12   13:a1   12:5  
            13   14:a1   13:5  
            14   15:a1   13:3  
            15   16:b1   14:2  
            16   17:a1   14:3  
            17   18:a1   15:5  
            18   19:a1   17:5  
            19   20:a1   18:5  
            20   23:a1   19:5  
            21   21:a1   20:3  
            22   22:a1   20:5  
            23   24:b1   21:2  
            24   25:b1   22:2  
            25   26:a1   23:5  
            26   28      24:5  
            27   27      25:5  
            28   29:b1   26:2  
            29   30      29:5
BRACKET     1 -11.5  -4.5 -11.5  -6.3
            1  -6.6  -6.3  -6.6  -4.5
            1 w
            2 -20.2 -10.9 -20.2 -13.1
            2 -14.8 -13.2 -14.8 -11.0
            2 v
            3  34.4  15.3  34.4  11.9
            3  40.8  11.8  40.8  15.2
            3 n
            4  24.6  15.1  24.6  11.5
            4  30.7  11.5  30.7  15.1
            4 m
            5  -1.6  -6.0  -1.6  -8.2
            5   4.0  -4.0   4.0  -2.0
            5 p
            6   6.2   0.4   6.2  -2.3
            6  11.5   1.8  11.5   4.5
            6 o
            7 -10.5 -12.9 -10.5 -15.3
            7  -5.0 -11.1  -5.0  -8.7
            7 q
            8 -12.0 -14.4 -12.0 -17.2
            8  13.2   3.5  13.2   6.3
            8 r
            9  23.3  15.9  23.3  10.7
            9  42.2  10.6  42.2  15.8
            9 l

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