KEGG   ORTHOLOGY: K23669
Entry
K23669                      KO                                     

Name
besD
Definition
L-lysine 4-chlorinase [EC:1.14.20.-]
Pathway
ko00997  Biosynthesis of various secondary metabolites - part 3
ko01100  Metabolic pathways
ko01110  Biosynthesis of secondary metabolites
Module
M00906  Ethynylserine biosynthesis, lysine => ethynylserine
Brite
KEGG Orthology (KO) [BR:ko00001]
 09100 Metabolism
  09110 Biosynthesis of other secondary metabolites
   00997 Biosynthesis of various secondary metabolites - part 3
    K23669  besD; L-lysine 4-chlorinase
Enzymes [BR:ko01000]
 1. Oxidoreductases
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.20  With 2-oxoglutarate as one donor, and the other dehydrogenated
    1.14.20.-  
     K23669  besD; L-lysine 4-chlorinase
Other DBs
RN: R12407
Genes
SCT: SCAT_p1048(arpA)
SCY: SCATT_p06880
Reference
  Authors
Marchand JA, Neugebauer ME, Ing MC, Lin CI, Pelton JG, Chang MCY
  Title
Discovery of a pathway for terminal-alkyne amino acid biosynthesis.
  Journal
Nature 567:420-424 (2019)
DOI:10.1038/s41586-019-1020-y
  Sequence

KEGG   REACTION: R12407
Entry
R12407                      Reaction                               

Name
L-lysine,2-oxoglutarate:oxygen oxidoreductase (4-halogenating)
Definition
L-Lysine + 2-Oxoglutarate + Oxygen + Cl- + H+ <=> 4-Chloro-L-lysine + Succinate + CO2 + H2O
Equation
Reaction class
RC03540  C00047_C22137
Enzyme
1.14.20.-
Pathway
rn00997  Biosynthesis of various secondary metabolites - part 3
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00906  Ethynylserine biosynthesis, lysine => ethynylserine
Orthology
K23669  L-lysine 4-chlorinase [EC:1.14.20.-]

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