KEGG   MODULE: M00834
Entry
M00834            Pathway   Module                                 

Name
Calicheamicin orsellinate moiety biosynthesis, malonyl-CoA => orsellinate-ACP => 5-iodo-2,3-dimethoxyorsellinate-ACP
Definition
K21254 K21255 K21256 K21257 K21258
Diagram
M00834

Orthology
K21254  
calO5; orsellinic acid synthase [EC:2.3.1.-] [RN:R11412]
K21255  
calO6; orsellinic acid C2-O-methyltransferase [EC:2.1.1.-] [RN:R11413]
K21256  
calO3; flavin-dependent halogenase [RN:R11414]
K21257  
calO2; orsellenic acid P450 oxidase [EC:1.14.-.-] [RN:R11415]
K21258  
calO1; orsellinic acid C3-O-methyltransferase [EC:2.1.1.-] [RN:R11416]
Class
Pathway modules; Biosynthesis of terpenoids and polyketides; Enediyne biosynthesis
Pathway
map01059  Biosynthesis of enediyne antibiotics
map01100  Metabolic pathways
map01110  Biosynthesis of secondary metabolites
Reaction
Compound
C00083  Malonyl-CoA
C21343  Orsellinate-[acp]
C21344  2-Methoxyorsellinate-[acp]
C21345  5-Iodo-2-methoxyorsellinate-[acp]
C21346  3-Hydroxy-5-iodo-2-methoxyorsellinate-[acp]
C21347  5-Iodo-2,3-dimethoxyorsellinate-[acp]

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