KEGG   REACTION: R00750
Entry
R00750                      Reaction                               

Name
4-hydroxy-2-oxopentanoate pyruvate-lyase (acetaldehyde-forming)
Definition
Acetaldehyde + Pyruvate <=> 4-Hydroxy-2-oxopentanoate
Equation
Reaction class
RC00307  C00022_C03589
RC00371  C00084_C03589
Enzyme
Pathway
rn00360  Phenylalanine metabolism
rn00362  Benzoate degradation
rn00621  Dioxin degradation
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Module
M00545  Trans-cinnamate degradation, trans-cinnamate => acetyl-CoA
M00569  Catechol meta-cleavage, catechol => acetyl-CoA / 4-methylcatechol => propanoyl-CoA
Orthology
K01666  4-hydroxy 2-oxovalerate aldolase [EC:4.1.3.39]
K18365  4-hydroxy-2-oxovalerate/4-hydroxy-2-oxohexanoate aldolase [EC:4.1.3.39 4.1.3.43]
Other DBs
RHEA: 22627

KEGG   RCLASS: RC00307
Entry
RC00307                     RClass                                 

Definition
C1a-C1b:*-C1c:C5a-C5a
Reactant pair
Related class
Reaction
Enzyme
4.1.2.14        4.1.2.18        4.1.2.20        4.1.2.21        
4.1.2.23        4.1.2.28        4.1.2.51        4.1.2.52        
4.1.2.53        4.1.2.54        4.1.2.55        4.1.2.58        
4.1.2.61        4.1.3.16        4.1.3.24        4.1.3.39        
4.1.3.42        4.1.3.43
Pathway
rn00030  Pentose phosphate pathway
rn00040  Pentose and glucuronate interconversions
rn00053  Ascorbate and aldarate metabolism
rn00330  Arginine and proline metabolism
rn00360  Phenylalanine metabolism
rn00362  Benzoate degradation
rn00621  Dioxin degradation
rn00622  Xylene degradation
rn00630  Glyoxylate and dicarboxylate metabolism
rn00680  Methane metabolism
rn00720  Carbon fixation pathways in prokaryotes
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01200  Carbon metabolism
rn01220  Degradation of aromatic compounds
RModule
RM034  Sugar degradation to aldehyde and pyruvate
Orthology
K01625  2-dehydro-3-deoxyphosphogluconate aldolase / (4S)-4-hydroxy-2-oxoglutarate aldolase [EC:4.1.2.14 4.1.3.42]
K01630  2-dehydro-3-deoxyglucarate aldolase [EC:4.1.2.20]
K01631  2-dehydro-3-deoxyphosphogalactonate aldolase [EC:4.1.2.21]
K01666  4-hydroxy 2-oxovalerate aldolase [EC:4.1.3.39]
K02510  4-hydroxy-2-oxoheptanedioate aldolase [EC:4.1.2.52]
K08691  malyl-CoA/(S)-citramalyl-CoA lyase [EC:4.1.3.24 4.1.3.25]
K11395  2-dehydro-3-deoxy-phosphogluconate/2-dehydro-3-deoxy-6-phosphogalactonate aldolase [EC:4.1.2.55]
K12660  2-dehydro-3-deoxy-L-rhamnonate aldolase [EC:4.1.2.53]
K17463  2-dehydro-3-deoxy-phosphogluconate aldolase [EC:4.1.2.14]
K18103  L-threo-3-deoxy-hexylosonate aldolase [EC:4.1.2.54]
K18123  4-hydroxy-2-oxoglutarate aldolase [EC:4.1.3.16]
K18127  2-dehydro-3-deoxy-D-gluconate aldolase [EC:4.1.2.51]
K18339  2-keto-3-deoxy-L-rhamnonate aldolase [EC:4.1.2.53]
K18365  4-hydroxy-2-oxovalerate/4-hydroxy-2-oxohexanoate aldolase [EC:4.1.3.39 4.1.3.43]
K18383  feruloyl-CoA hydratase/lyase [EC:4.1.2.61]
K19282  bifunctional (S)-malyl-CoA lyase/thioesterase [EC:4.1.3.24 3.1.2.30]
K22397  2-dehydro-3-deoxy-D-pentonate aldolase [EC:4.1.2.28]

KEGG   RCLASS: RC00371
Entry
RC00371                     RClass                                 

Definition
C1c-C4a:C1b-*:C1a+O1a-C1a+O4a
Reactant pair
Related class
Reaction
Enzyme
Pathway
rn00360  Phenylalanine metabolism
rn00362  Benzoate degradation
rn00621  Dioxin degradation
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
RModule
RM009  Meta-cleavage of dihydroxylated aromatic ring
Orthology
K01666  4-hydroxy 2-oxovalerate aldolase [EC:4.1.3.39]
K18365  4-hydroxy-2-oxovalerate/4-hydroxy-2-oxohexanoate aldolase [EC:4.1.3.39 4.1.3.43]

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