KEGG   REACTION: R02675
Entry
R02675                      Reaction                               

Name
4-methylphenol:oxidized azurin oxidoreductase (methyl-hydroxylating)
Definition
4-Cresol + 4 Oxidized azurin + H2O <=> 4-Hydroxybenzaldehyde + 4 Reduced azurin + 4 H+
Equation
C01468 + 4 C05357 + C00001 <=> C00633 + 4 C05358 + 4 C00080
Comment
two-step reaction (see R12133+R12134)
possibly intermediates (quinone methide and 4-hydroxybenzyl alcohol)
Reaction class
RC00769  C00633_C01468
Enzyme
Pathway
rn00623  Toluene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
Orthology
K05797  4-cresol dehydrogenase (hydroxylating) flavoprotein subunit [EC:1.17.9.1]
K20200  4-cresol dehydrogenase (hydroxylating) cytochrome subunit

KEGG   RCLASS: RC00769
Entry
RC00769                     RClass                                 

Definition
C1a-C4a:*-O4a:C8y-C8y
Reactant pair
Related class
Reaction
Enzyme
1.14.13.122     1.17.9.1        1.17.98.2       1.17.99.9       
2.6.1.114
Pathway
rn00623  Toluene degradation
rn00860  Porphyrin and chlorophyll metabolism
rn00997  Biosynthesis of various secondary metabolites - part 3
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01240  Biosynthesis of cofactors
Orthology
K02259  heme a synthase [EC:1.17.99.9]
K05797  4-cresol dehydrogenase (hydroxylating) flavoprotein subunit [EC:1.17.9.1]
K13600  chlorophyllide a oxygenase [EC:1.14.13.122]
K20200  4-cresol dehydrogenase (hydroxylating) cytochrome subunit
K21312  bacteriochlorophyllide c C-7(1)-hydroxylase [EC:1.17.98.2]
K22598  8-demethyl-8-aminoriboflavin-5'-phosphate synthase [EC:2.6.1.114]

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