KEGG   REACTION: R05292
Entry
R05292                      Reaction                               

Name
cis-1,2-Dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate:NAD+ oxidoreductase (decarboxylating)
Definition
cis-1,2-Dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate + NAD+ <=> 4-Methylcatechol + CO2 + NADH + H+
Equation
Reaction class
RC00001  C00003_C00004
RC00271  C06729_C06730
Enzyme
Pathway
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Module
M00551  Benzoate degradation, benzoate => catechol / methylbenzoate => methylcatechol
Orthology
K05783  dihydroxycyclohexadiene carboxylate dehydrogenase [EC:1.3.1.25 1.3.1.-]
Other DBs
RHEA: 24231

KEGG   REACTION: R05293
Entry
R05293                      Reaction                               

Name
cis-1,2-Dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate:NADP+ oxidoreductase (decarboxylating)
Definition
cis-1,2-Dihydroxy-4-methylcyclohexa-3,5-diene-1-carboxylate + NADP+ <=> 4-Methylcatechol + CO2 + NADPH + H+
Equation
Reaction class
RC00001  C00005_C00006
RC00271  C06729_C06730
Enzyme
Pathway
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Orthology
K05783  dihydroxycyclohexadiene carboxylate dehydrogenase [EC:1.3.1.25 1.3.1.-]
Other DBs
RHEA: 24227

KEGG   RCLASS: RC00271
Entry
RC00271                     RClass                                 

Definition
C1y-C8y:*-*:C1z+C2x+O1a-C8y+C8x+O1a
C1z-C8y:C6a-*:C1y+C2x+O1a-C8y+C8x+O1a
Reactant pair
Related class
Reaction
Enzyme
1.3.1.25        1.3.1.53        1.3.1.67
Pathway
rn00362  Benzoate degradation
rn00364  Fluorobenzoate degradation
rn00622  Xylene degradation
rn00624  Polycyclic aromatic hydrocarbon degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
RModule
RM005  Dihydroxylation of aromatic ring, type 1a (dioxygenase and decarboxylating dehydrogenase reactions)
Orthology
K05783  dihydroxycyclohexadiene carboxylate dehydrogenase [EC:1.3.1.25 1.3.1.-]
K18076  1,2-dihydroxy-3,5-cyclohexadiene-1,4-dicarboxylate dehydrogenase [EC:1.3.1.53]

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