KEGG   REACTION: R05353
Entry
R05353                      Reaction                               

Name
2-hydroxy-5-methyl-cis,cis-muconic semialdehyde:NAD+ 6-oxidoreductase
Definition
2-Hydroxy-5-methyl-cis,cis-muconic semialdehyde + NAD+ + H2O <=> 2-Hydroxy-5-methyl-cis,cis-muconate + NADH + H+
Equation
Reaction class
RC00001  C00003_C00004
RC00254  C06760_C07478
Enzyme
Pathway
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Module
M00569  Catechol meta-cleavage, catechol => acetyl-CoA / 4-methylcatechol => propanoyl-CoA
Orthology
K10217  aminomuconate-semialdehyde/2-hydroxymuconate-6-semialdehyde dehydrogenase [EC:1.2.1.32 1.2.1.85]

KEGG   RCLASS: RC00254
Entry
RC00254                     RClass                                 

Definition
C4a-C6a:*-O6a:C2c+O4a-C2c+O6a
Reactant pair
Related class
Reaction
Enzyme
1.1.1.312       1.2.1.60        1.2.1.82        1.2.1.85        
1.2.1.-         1.2.99.10       1.14.14.95      1.14.14.114     
1.14.99.44
Pathway
rn00350  Tyrosine metabolism
rn00622  Xylene degradation
rn00903  Limonene and pinene degradation
rn00906  Carotenoid biosynthesis
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
RModule
RM009  Meta-cleavage of dihydroxylated aromatic ring
RM012  Dihydroxylation and meta-cleavage of aromatic ring, type 3a
Orthology
K00151  5-carboxymethyl-2-hydroxymuconic-semialdehyde dehydrogenase [EC:1.2.1.60]
K10210  diapolycopene oxygenase [EC:1.14.99.44]
K10217  aminomuconate-semialdehyde/2-hydroxymuconate-6-semialdehyde dehydrogenase [EC:1.2.1.32 1.2.1.85]
K10219  2-hydroxy-4-carboxymuconate semialdehyde hemiacetal dehydrogenase [EC:1.1.1.312]
K17819  beta-apo-4'-carotenal oxygenase [EC:1.2.1.82]

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