KEGG   REACTION: R05470
Entry
R05470                      Reaction                               

Definition
Clavaminic acid <=> Clavulanate-9-aldehyde
Equation
Comment
enzyme not yet characterized
deamination, double epimerisation
Reaction class
RC01392  C06660_C06661
Pathway
rn00331  Clavulanic acid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Reference
1  [PMID:9614345]
  Authors
McGowan SJ, Bycroft BW, Salmond GP.
  Title
Bacterial production of carbapenems and clavams: evolution of beta-lactam antibiotic pathways.
  Journal
Trends Microbiol 6:203-8 (1998)
DOI:10.1016/S0966-842X(98)01251-7
Other DBs
RHEA: 42431

KEGG   RCLASS: RC01392
Entry
RC01392                     RClass                                 

Definition
C1b-C4a:N1a+*-*+O4a:C2b-C2b
C1y-C1y:*-*:C1x+N1y+O2x-C1x+N1y+O2x
C1y-C1y:*-*:C2y+C6a+N1y-C2y+C6a+N1y
Reactant pair
Related class
Reaction
Pathway
rn00331  Clavulanic acid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites

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