KEGG   REACTION: R08935
Entry
R08935                      Reaction                               

Name
dTDP-6-deoxy-L-mannose:NADP+ 4-oxidoreductase (3,5-epimerizing)
Definition
dTDP-L-rhamnose + NADP+ <=> dTDP-4-oxo-6-deoxy-D-glucose + NADPH + H+
Equation
Comment
two-step reaction (see R06514+R02777)
Reaction class
RC00001  C00005_C00006
RC01014  C03319_C11907
Enzyme
1.1.1.-
Pathway
rn00523  Polyketide sugar unit biosynthesis
rn01110  Biosynthesis of secondary metabolites
Orthology
K12451  3,5-epimerase/4-reductase [EC:5.1.3.- 1.1.1.-]

KEGG   RCLASS: RC01014
Entry
RC01014                     RClass                                 

Definition
C1y-C1y:*-*:C1a+C1y+O2x-C1a+C5x+O2x
C1y-C1y:*-*:C1y+C1y+O1a-C1y+C5x+O1a
C1y-C5x:*-*:C1y+C1y+O1a-C1y+C1y+O5x
Reactant pair
Related class
Reaction
Enzyme
1.1.1.271       1.1.1.-
Pathway
rn00051  Fructose and mannose metabolism
rn00520  Amino sugar and nucleotide sugar metabolism
rn00523  Polyketide sugar unit biosynthesis
rn00541  O-Antigen nucleotide sugar biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K02377  GDP-L-fucose synthase [EC:1.1.1.271]
K12451  3,5-epimerase/4-reductase [EC:5.1.3.- 1.1.1.-]

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