KEGG   REACTION: R10453
Entry
R10453                      Reaction                               

Name
3-dimethylallyl-4-hydroxybenzoate:3-amino-4,7-dihydroxycoumarin ligase (AMP-forming)
Definition
ATP + 3-Dimethylallyl-4-hydroxybenzoate + 3-Amino-4,7-dihydroxycoumarin <=> AMP + Diphosphate + 8-Demethylnovobiocic acid
Equation
Reaction class
RC00162  C12458_C20629
RC00416  C12468_C20629
Enzyme
Pathway
rn00401  Novobiocin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K12709  8-demethylnovobiocic acid synthase [EC:6.3.1.15]
Other DBs
RHEA: 36702

KEGG   RCLASS: RC00416
Entry
RC00416                     RClass                                 

Definition
N1a-N1b:*-C5a:C8y-C8y
Reactant pair
Related class
Reaction
Enzyme
2.3.1.5         2.3.1.113       2.3.1.114       2.3.1.144       
2.3.1.234       3.1.1.1         3.5.1.13        3.5.1.72        
3.5.1.123       3.5.3.-         6.3.1.15        6.3.1.18
Pathway
rn00230  Purine metabolism
rn00401  Novobiocin biosynthesis
rn00633  Nitrotoluene degradation
rn00982  Drug metabolism - cytochrome P450
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
Orthology
K00622  arylamine N-acetyltransferase [EC:2.3.1.5]
K01409  N6-L-threonylcarbamoyladenine synthase [EC:2.3.1.234]
K12709  8-demethylnovobiocic acid synthase [EC:6.3.1.15]
K15904  bifunctional N6-L-threonylcarbamoyladenine synthase / protein kinase Bud32 [EC:2.3.1.234 2.7.11.1]
K21287  gamma-glutamylanilide hydrolase [EC:3.5.1.123]

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