KEGG   REACTION: R10656
Entry
R10656                      Reaction                               

Name
20-oxo-5-O-beta-mycaminosyltylactone,reduced ferredoxin:oxygen oxidoreductase (23-hydroxylating)
Definition
20-Oxo-5-O-beta-mycaminosyltylactone + 2 Reduced ferredoxin + 2 H+ + Oxygen <=> 5-O-beta-D-Mycaminosyltylonolide + 2 Oxidized ferredoxin + H2O
Equation
Reaction class
RC03228  C12002_C20760
Enzyme
Pathway
rn00522  Biosynthesis of 12-, 14- and 16-membered macrolides
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00773  Tylosin biosynthesis, methylmalonyl-CoA + malonyl-CoA => tylactone => tylosin
Orthology
K15991  20-oxo-5-O-mycaminosyltylactone 23-monooxygenase [EC:1.14.15.34]
Other DBs
RHEA: 24527

KEGG   RCLASS: RC03228
Entry
RC03228                     RClass                                 

Definition
C1a-C1b:*-O1a:C1y-C1y
Reactant pair
Related class
Reaction
Enzyme
1.14.13.-       1.14.15.34      1.14.18.11      1.14.99.62
Pathway
rn00522  Biosynthesis of 12-, 14- and 16-membered macrolides
rn00999  Biosynthesis of various secondary metabolites - part 1
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K15991  20-oxo-5-O-mycaminosyltylactone 23-monooxygenase [EC:1.14.15.34]
K22998  cyclooctatin synthase [EC:1.14.99.62]
K24292  mycinamicin VIII C21 methyl hydroxylase [EC:1.14.-.-]
K24530  ferredoxin

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