KEGG   REACTION: R10956
Entry
R10956                      Reaction                               

Name
S-adenosyl-L-methionine:8-demethyl-8-alpha-L-rhamnosyltetracenomycin-C 2'-O-methyltransferase
Definition
S-Adenosyl-L-methionine + 8-Demethyl-8-alpha-L-rhamnosyltetracenomycin C <=> S-Adenosyl-L-homocysteine + 8-Demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)tetracenomycin C
Equation
Reaction class
RC00003  C00019_C00021
RC00466  C20974_C20975
Enzyme
Pathway
rn01057  Biosynthesis of type II polyketide products
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00784  Elloramycin biosynthesis, 8-demethyltetracenomycin C => elloramycin A
Orthology
K19567  8-demethyl-8-alpha-L-rhamnosyltetracenomycin-C 2'-O-methyltransferase [EC:2.1.1.305]

KEGG   RCLASS: RC00466
Entry
RC00466                     RClass                                 

Definition
O1a-O2a:*-C1a:C1y-C1y
Reactant pair
Related class
Reaction
Enzyme
2.1.1.34        2.1.1.39        2.1.1.40        2.1.1.57        
2.1.1.101       2.1.1.102       2.1.1.112       2.1.1.129       
2.1.1.139       2.1.1.164       2.1.1.237       2.1.1.238       
2.1.1.239       2.1.1.285       2.1.1.296       2.1.1.305       
2.1.1.306       2.1.1.307       2.1.1.-
Pathway
rn00401  Novobiocin biosynthesis
rn00404  Staurosporine biosynthesis
rn00522  Biosynthesis of 12-, 14- and 16-membered macrolides
rn00523  Polyketide sugar unit biosynthesis
rn00562  Inositol phosphate metabolism
rn01057  Biosynthesis of type II polyketide products
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K12712  demethyldecarbamoylnovobiocin O-methyltransferase [EC:2.1.1.285]
K13320  L-olivosyl-oleandolide 3-O-methyltransferase [EC:2.1.1.239]
K14374  avermectin B 5-O-methyltransferase [EC:2.1.1.-]
K14589  cap1 methyltransferase [EC:2.1.1.57]
K14590  cap2 methyltransferase [EC:2.1.1.296]
K15959  O-methyltransferase [EC:2.1.1.-]
K15995  demethylmacrocin O-methyltransferase [EC:2.1.1.102]
K15996  macrocin O-methyltransferase [EC:2.1.1.101]
K18776  cap2 methyltransferase [EC:2.1.1.296]
K19567  8-demethyl-8-alpha-L-rhamnosyltetracenomycin-C 2'-O-methyltransferase [EC:2.1.1.305]
K19568  8-demethyl-8-(2-methoxy-alpha-L-rhamnosyl)tetracenomycin-C 3'-O-methyltransferase [EC:2.1.1.306]
K19569  8-demethyl-8-(2,3-dimethoxy-alpha-L-rhamnosyl)tetracenomycin-C 4'-O-methyltransferase [EC:2.1.1.307]
K19856  3-O-methyltransferase [EC:2.1.1.-]
K19889  demethylrebeccamycin-D-glucose O-methyltransferase [EC:2.1.1.164]
K20082  O-methyltransferase StaMB [EC:2.1.1.139]
K21325  dTDP-rhamnose C3-O-methyltransferase [EC:2.1.1.-]
K21539  mycinamicin III 3''-O-methyltransferase [EC:2.1.1.237]
K21540  mycinamicin VI 2''-O-methyltransferase [EC:2.1.1.238]

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