KEGG   REACTION: R10959
Entry
R10959                      Reaction                               

Name
S-adenosyl-L-methionine:8-demethyl-8-(2,3,4-tri-O-methyl-alpha-L-rhamnosyl)tetracenomycin-C O-methyltransferase
Definition
S-Adenosyl-L-methionine + 8-Demethyl-8-(2,3,4-tri-O-methyl-alpha-L-rhamnosyl)tetracenomycin C <=> S-Adenosyl-L-homocysteine + Elloramycin A
Equation
Reaction class
RC00003  C00019_C00021
RC01324  C12381_C20977
Enzyme
2.1.1.-
Pathway
rn01057  Biosynthesis of type II polyketide products
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00784  Elloramycin biosynthesis, 8-demethyltetracenomycin C => elloramycin A
Orthology
K19570  8-demethyl-8-(2,3,4-trimethoxy-alpha-L-rhamnosyl)tetracenomycin-C O-methyltransferase [EC:2.1.1.-]

KEGG   RCLASS: RC01324
Entry
RC01324                     RClass                                 

Definition
O1a-O2a:*-C1a:C1z-C1z
Reactant pair
Related class
Reaction
Enzyme
2.1.1.254       2.1.1.-
Pathway
rn00311  Penicillin and cephalosporin biosynthesis
rn00522  Biosynthesis of 12-, 14- and 16-membered macrolides
rn01057  Biosynthesis of type II polyketide products
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K14369  erythromycin 3''-O-methyltransferase [EC:2.1.1.254]
K18062  cephamycin C biosynthesis protein
K19570  8-demethyl-8-(2,3,4-trimethoxy-alpha-L-rhamnosyl)tetracenomycin-C O-methyltransferase [EC:2.1.1.-]

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