KEGG   REACTION: R11368
Entry
R11368                      Reaction                               

Name
(S)-beta-tyrosyl-[pcp]:FADH2 oxidoreductase
Definition
(S)-beta-Tyrosyl-[pcp] + FADH2 + Cl- + Oxygen + H+ <=> (S)-3-Chloro-beta-tyrosyl-[pcp] + FAD + 2 H2O
Equation
Reaction class
RC00949  C20810_C21309
Enzyme
1.14.19.-
Pathway
rn01059  Biosynthesis of enediyne antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00827  C-1027 beta-amino acid moiety biosynthesis, tyrosine => 3-chloro-4,5-dihydroxy-beta-phenylalanyl-PCP
Orthology
K16431  FAD-dependent halogenase [EC:1.14.19.-]
K21185  flavin reductase

KEGG   RCLASS: RC00949
Entry
RC00949                     RClass                                 

Definition
C8x-C8y:*-X:C8x+C8y-C8x+C8y
Reactant pair
Related class
Reaction
Enzyme
1.11.1.8        1.14.14.-       1.14.19.9       1.14.19.49      
1.14.19.55      1.14.19.56      1.14.19.57      1.14.19.60      
1.14.19.-       1.21.1.1        1.21.1.2        1.21.99.3       
1.21.99.4       1.97.1.-        2.5.1.-
Pathway
rn00253  Tetracycline biosynthesis
rn00350  Tyrosine metabolism
rn00361  Chlorocyclohexane and chlorobenzene degradation
rn00363  Bisphenol degradation
rn00364  Fluorobenzoate degradation
rn00404  Staurosporine biosynthesis
rn01057  Biosynthesis of type II polyketide products
rn01059  Biosynthesis of enediyne antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
Orthology
K00431  thyroid peroxidase [EC:1.11.1.8]
K14257  tetracycline 7-halogenase / FADH2 O2-dependent halogenase [EC:1.14.19.49 1.14.19.-]
K14266  tryptophan 7-halogenase [EC:1.14.19.9]
K15239  2,5-dichlorohydroquinone reductive dechlorinase [EC:2.5.1.-]
K16431  FAD-dependent halogenase [EC:1.14.19.-]
K21185  flavin reductase

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