Entry |
|
Name |
5-O-beta-D-Mycaminosyltylonolide
|
Formula |
C31H51NO10
|
Exact mass |
597.3513
|
Mol weight |
597.74
|
Structure |
|
Sequence |
0 Mtk 1 Mtd 2 Mtd 3 Man 4 Mte 5 Etk 6 Mtk 7 Man |
Gene |
|
Organism |
Streptomyces fradiae |
Type |
PK |
Reaction |
|
Pathway |
map00522 | Biosynthesis of 12-, 14- and 16-membered macrolides |
map01110 | Biosynthesis of secondary metabolites |
|
Module |
M00773 | Tylosin biosynthesis, methylmalonyl-CoA + malonyl-CoA => tylactone => tylosin |
|
Enzyme |
|
Brite |
Lipids [BR:br08002]
PK Polyketides
PK04 Macrolides and lactone polyketides
C12002 5-O-beta-D-Mycaminosyltylonolide
|
Other DBs |
|
KCF data |
ATOM 42
1 C1y C 27.2748 -25.6018
2 C1y C 28.4076 -26.2634
3 C1y C 27.2748 -24.2961
4 C1y C 29.5462 -25.6018
5 N1c N 28.4076 -27.5690
6 O2x O 28.4076 -23.6404
7 C1a C 26.1482 -23.6404
8 C1y C 29.5462 -24.2961
9 O1a O 30.6848 -26.2634
10 O2a O 31.5314 -22.3170
11 C1y C 29.4985 -19.7712
12 C1y C 29.4865 -18.4359
13 C1y C 28.3419 -20.4569
14 C1x C 28.3241 -17.7862
15 C1b C 30.6193 -17.7743
16 C1y C 28.3479 -21.8042
17 C1a C 27.2987 -19.6879
18 C1y C 28.3241 -16.4567
19 C1x C 27.1794 -22.4779
20 O1a O 29.4865 -22.4541
21 C5x C 27.1735 -15.8233
22 C1a C 29.4568 -15.8150
23 C7x C 26.0228 -21.7625
24 C2x C 26.0408 -16.4567
25 O5x O 27.1735 -14.5043
26 O7x O 24.8603 -22.4361
27 O6a O 26.0111 -20.4450
28 C2x C 26.0408 -17.7862
29 C1y C 23.7278 -21.7445
30 C2y C 24.8842 -18.4359
31 C1y C 23.7098 -20.4270
32 C1b C 22.5593 -22.4183
33 C2x C 24.8664 -19.7534
34 C1a C 23.7516 -17.7862
35 C1b C 22.5712 -19.7654
36 C1a C 27.2767 -28.2218
37 C1a C 29.5382 -28.2218
38 O1a O 26.1371 -26.2549
39 C4a C 31.7586 -18.4245
40 O4a O 32.8913 -17.7629
41 O1a O 21.4288 -20.4206
42 C1a C 22.5584 -23.7671
BOND 43
1 4 8 1
2 4 9 1 #Down
3 8 10 1 #Up
4 11 10 1 #Down
5 11 12 1
6 11 13 1
7 12 14 1
8 12 15 1 #Down
9 13 16 1
10 13 17 1 #Down
11 14 18 1
12 16 19 1
13 16 20 1 #Down
14 18 21 1
15 18 22 1 #Down
16 19 23 1
17 21 24 1
18 21 25 2
19 23 26 1
20 23 27 2
21 24 28 2
22 26 29 1
23 28 30 1
24 29 31 1
25 29 32 1 #Down
26 30 33 2
27 30 34 1
28 31 35 1 #Up
29 6 8 1
30 31 33 1
31 5 36 1
32 1 2 1
33 5 37 1
34 1 3 1
35 1 38 1 #Down
36 2 4 1
37 15 39 1
38 2 5 1 #Up
39 39 40 2
40 3 6 1
41 35 41 1
42 3 7 1 #Up
43 32 42 1
|