Oxidoreductases;
Acting on paired donors, with incorporation or reduction of molecular oxygen;
With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
BRITE hierarchy

2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (cyclizing)

(1) 2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH---hemoprotein reductase] + O2 = glyceollin II + [oxidized NADPH---hemoprotein reductase] + 2 H2O [RN:R07195];
(2) 2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH---hemoprotein reductase] + O2 = glyceollin III + [oxidized NADPH---hemoprotein reductase] + 2 H2O [RN:R07196];
(3) 4-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH---hemoprotein reductase] + O2 = glyceollin I + [oxidized NADPH---hemoprotein reductase] + 2 H2O [RN:R07197]

R07195 R07196 R07197;
(other) R07356 R07357
Reaction

2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan [CPD:C15509];
[reduced NADPH---hemoprotein reductase] [CPD:C03024];
O2 [CPD:C00007];
4-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan [CPD:C15510]

A cytochrome P-450 (heme-thiolate) protein purified from soybean.

EC 1.14.14.135 created 2004 as EC 1.14.13.85, transferred 2018 to EC 1.14.14.135

1  [PMID:3369863]

Welle R, Grisebach H.

Induction of phytoalexin synthesis in soybean: enzymatic cyclization of prenylated pterocarpans to glyceollin isomers.

Arch Biochem Biophys 263:191-8 (1988)
DOI:10.1016/0003-9861(88)90627-3