Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
Sysname
[glycine cleavage system H]-N6-octanoyl-L-lysine:[lipoyl-carrier protein]-N6-L-lysine octanoyltransferase
Reaction(IUBMB)
[glycine cleavage system H]-N6-octanoyl-L-lysine + a [lipoyl-carrier protein] = glycine cleavage system H + a [lipoyl-carrier protein]-N6-octanoyl-L-lysine [RN:R12425]
[glycine cleavage system H]-N6-octanoyl-L-lysine [CPD:C22159];
[lipoyl-carrier protein]
Product
glycine cleavage system H [CPD:C22157];
[lipoyl-carrier protein]-N6-octanoyl-L-lysine
Comment
In the bacterium Bacillus subtilis it has been shown that the enzyme catalyses the
amidotransfer of the octanoyl moiety from [glycine cleavage system H]-N6-octanoyl-L-lysine (i.e. octanoyl-GcvH) to the E2 subunit (dihydrolipoamide acetyltransferase) of pyruvate dehydrogenase.
