Entry Name anthocyanidin 3-O-glucoside 6''-O-acyltransferase
Class Transferases;BRITE hierarchy
Sysname 4-hydroxycinnamoyl-CoA:anthocyanin-3-O-glucoside 6''-O-acyltransferase
Reaction(IUBMB) 4-hydroxycinnamoyl-CoA + an anthocyanidin 3-O-beta-D-glucoside = CoA + an anthocyanidin 3-O-[6-O-(4-hydroxycinnamoyl)-beta-D-glucoside] [RN:
R10237 ]
Reaction(KEGG) Substrate 4-hydroxycinnamoyl-CoA [CPD:
C00223 ];
anthocyanidin 3-O-beta-D-glucoside [CPD:
C15539 ]
Product CoA [CPD:
C00010 ];
anthocyanidin 3-O-[6-O-(4-hydroxycinnamoyl)-beta-D-glucoside] [CPD:
C20461 ]
Comment Isolated from the plants Perilla frutescens and Gentiana triflora (clustered gentian). Acts on a range of anthocyanidin 3-O-glucosides, 3,5-di-O-glucosides and cyanidin 3-rutinoside. It did not act on delphinidin 3,3',7-tri-O-glucoside. Recombinant Perilla frutescens enzyme could utilize caffeoyl-CoA but not malonyl-CoA as alternative acyl donor.
History EC 2.3.1.215 created 2013
Pathway ec01110 Biosynthesis of secondary metabolites
Orthology K21383 anthocyanidin 3-O-glucoside 6''-O-acyltransferase
Genes SSPL : 121784110 121787691 121802934
SMIL : 131012594 131012595 131012596
SHIS : 125195271 125209448
APAN : 127240404 127258502
Taxonomy Reference 1
Authors Fujiwara H, Tanaka Y, Fukui Y, Ashikari T, Yamaguchi M, Kusumi T.
Title Purification and characterization of anthocyanin 3-aromatic acyltransferase from Perilla frutescens.
Journal Plant Sci 137:87-94 (1998)
Reference Authors Yonekura-Sakakibara K, Tanaka Y, Fukuchi-Mizutani M, Fujiwara H, Fukui Y, Ashikari T, Murakami Y, Yamaguchi M, Kusumi T
Title Molecular and biochemical characterization of a novel hydroxycinnamoyl-CoA: anthocyanin 3-O-glucoside-6"-O-acyltransferase from Perilla frutescens.
Journal Sequence Other DBs ExPASy - ENZYME nomenclature database: 2.3.1.215
