KEGG ENZYME: 2.3.1.232

ENZYME: 2.3.1.232

Entry

EC 2.3.1.232                Enzyme

Name

methanol O-anthraniloyltransferase;
AMAT;
anthraniloyl-coenzyme A (CoA):methanol acyltransferase

Class

Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups

Sysname

anthraniloyl-CoA:methanol O-anthraniloyltransferase

Reaction(IUBMB)

anthraniloyl-CoA + methanol = CoA + O-methyl anthranilate [RN:R10681]

Reaction(KEGG)

R10681

Substrate

anthraniloyl-CoA [CPD:C02247];
methanol [CPD:C00132]

Product

CoA [CPD:C00010];
O-methyl anthranilate [CPD:C20634]

Comment

The enzyme from Concord grape (Vitis labrusca) is solely responsible for the production of O-methyl anthranilate, an important aroma and flavor compound in the grape. The enzyme has a broad substrate specificity, and can use a range of alcohols with substantial activity, the best being butanol, benzyl alcohol, iso-pentanol, octanol and 2-propanol. It can use benzoyl-CoA and acetyl-CoA as acyl donors with lower efficiency. In addition to O-methyl anthranilate, the enzyme might be responsible for the production of ethyl butanoate, methyl-3-hydroxy butanoate and ethyl-3-hydroxy butanoate, which are present in large quantities in the grapes. Also catalyses EC 2.3.1.196, benzyl alcohol O-benzoyltransferase.

History

EC 2.3.1.232 created 2014

Orthology

K19861

benzyl alcohol O-benzoyltransferase

Genes

ATH:

AT5G17540

ALY:

9307841

CRB:	17882598 17883284

CSAT:

104706051 104706052 104735796 104735797 104770061 104770062

EUS:	EUTSA_v10013454mg

BRP:

103856254

BNA:

106383453

BOE:

106328018

RSZ:

108832398

CIT:

102630782

CIC:	CICLE_v10031489mg

PVY:	116108988 116109446 116111856 116120760 116132506 116134533 116143617

MINC:

123202107 123205894 123206522 123206984 123209065 123209066 123209718 123226548

EGR:

104427024

GMX:	100797017 100799685

GSJ:	114372437 114377355

PVU:	PHAVU_007G280800g

VRA:

106769599

VAR:

108324959

VUN:

114191882

CCAJ:

109815603

APRC:

113872425

MTR:

25482870

TPRA:

123892364 123908484 123908494 123908514

CAM:

101508133

PSAT:

127093140 127093155 127093156 127093157 127093158 127095106 127095109 127095110 127095111

ADU:

107462813

AIP:

107613431

AHF:	112695465 112707618 112758228 112771083

LANG:

109325685 109352521

FVE:

101297794

RCN:

112173156

PMUM:

103331665

PAVI:

110755953

PDUL:

117621834 117628550 117637259

MDM:	103423207 103423220

MSYL:

126583181 126592750 126614049 126614050 126614301 126625926 126625939 126625940 126627101 126627102 126627103

PXB:	103961715 103963031

ZJU:

107432782

MNT:	112091470 21405595 21409773 21409849

CSAV:

115700764 115715775 115717037 115725665 115725666

CSV:

101205621

CMO:

103501099

BHJ:	120087706 120087771 120087980 120088300 120088899 120089052 120089185 120089279 120089324

MCHA:

111017149

CMAX:

111484237 111499875

CMOS:

111448233 111451858

CPEP:

111776990 111794567

RCU:	8284276 8284279

JCU:

105632501

HBR:

110651562

MESC:

110622159

POP:	18104173 18110648 7482422 7491087 7491394 7491399 7491401

PEU:	105114396 105114397 105117135 105137147

PALZ:

118027786 118027997 118032160 118032162 118032163 118032164 118035537 118038636 118046065 118046104 118046105 118052585 118053573 118053577 118059527 118061191

JRE:	108980409 108980410 108980636 108980779 108988616 108996627 109007491 109007493

CILL:

122310877 122312541 122312915 122312983 122313032 122314008

QSU:	111989464 111989482 111989491 111989496 111989499 112009113 112028909 112029064 112029458 112038642 112038657

QLO:	115959143 115959195 115960571 115960624 115960709 115961354 115961355 115961793 115962116 115962253 115970909 115972495

TWL:	119997464 120016514 120016515 120016516

VVI:	100243166 100252759 100257911 100260288 100261281 100263045 100266675

VRI:	117909762 117910166 117922686 117927476 117928444 117928972 117929179 117934012 117934019 117934029 117934038 117934171

SLY:	101261933 101262227

SPEN:

107024327 107024360

SSTN:

125877106 125877107

CANN:

107877868

NTA:	107776214 107814928(hsr201) 107824435

NSY:	104248830 104249987

NTO:

104111677

NAU:

109212944

INI:	109155691 109156148 109164130 109164131 109187227 109187325

ITR:	115995617 116009674 116009683 116009684 116010715 116011308 116011310 116011311 116026764 116027563 116027719 116028080 116031593

SIND:

105167776

OEU:

111379669

EGT:	105953381 105953385 105953388 105953391 105953392 105961158 105969782

SSPL:

121763559 121763571 121763620 121778555 121781376 121781377 121783629 121784371 121785783 121785886

APAN:

127242310 127242362 127250396 127250430

ECAD:

122581843 122582139 122582266 122582887 122582986 122583605 122599756 122602110 122602247 122602260

DCR:

108207978

CSIN:

114261072 114263020 114263029 114263031 114264229 114268121 114279762 114290041 114290110 114303439 114305119 114323378

BVG:

104889262

SOE:

110792434

CQI:	110705198 110718858

NNU:

104610311

MING:

122057711 122072760 122073246 122074738 122081117

TSS:	122644555 122648611 122657503 122659087 122659319

PSOM:

113297455

OSA:	4326476 4337762 4342032 4342820 4343545 4348049 4348247 4349050

DOSA:

Os06t0710700-01(Os06g0710700) Os07t0550600-01(Os07g0550600) Os10t0133500-01(Os10g0133500) Os10t0195600-01(Os10g0195600)

OBR:	102708653 102714107 102714387 102720062

OGL:	127775670 127780481 127786156 127786235 127786258

BDI:	100827400 100830188 100843790

ATS:	109735002 109738690 109745656 109751661 109755369 109755385 109767173 109768200

TDC:	119271002 119280655 119283947 119289958 119294040 119298555 119316564 119327333 119331165 119332352 119335476 119338270 119345240

TAES:

123048034 123057108 123077894 123083508 123083515 123084277 123084464 123084848 123089363 123100722 123107713 123108535 123123223 123125445 123125446 123134501 123148512 123151462 123152503 123156821 123162391 123162847 123163757 123167869 123168415 123169258 123170127 123180371 123181204 123182127

TUA:	125505952 125509205 125509232 125515739 125522900 125523887 125523965 125524526 125525112 125525135 125532885 125535574 125554279 125556613

LPER:

127297255 127298411 127302869 127302889 127302940 127302943 127303689 127312935 127313174 127348516

SBI:	8064973 8065604 8065605 8067081

ZMA:	100286158 103626437 103653280

SITA:

101759181 101771750 101772151 101778271 101785522

SVS:	117835585 117840614 117840719 117851806 117854030

PVIR:

120643935 120644192 120644514 120646157 120646280 120648707 120650591 120651282 120666063 120666074 120668767 120669498 120678255 120686181 120687926 120691992 120692300 120692871 120699328 120699331 120699332 120704449

PHAI:

112876639 112889564 112890226

PDA:	103699757 120104448

EGU:	105059707 105059710

MUS:

103975095

ZOF:	121967089 121970577 121972616 121972619 121972620 121973553 121973555 121977754 121977755 121977758 121977759 121978430 122002029 122006282 122032722 122034672

NCOL:

116252322

ATR:

18422709

» show all

Reference

1 [PMID:16262710]

Authors

Wang J, De Luca V

Title

The biosynthesis and regulation of biosynthesis of Concord grape fruit esters, including 'foxy' methylanthranilate.

Journal

Plant J 44:606-19 (2005)
DOI:10.1111/j.1365-313X.2005.02552.x

Sequence

[ag:AAW22989]

Other DBs

ExplorEnz - The Enzyme Database:

2.3.1.232

IUBMB Enzyme Nomenclature:

2.3.1.232

ExPASy - ENZYME nomenclature database:

2.3.1.232

BRENDA, the Enzyme Database:

2.3.1.232

All links

Chemical substance (4)   
   KEGG COMPOUND (4)   
Chemical reaction (3)   
   KEGG REACTION (1)   
   KEGG RCLASS (2)   
Gene (479)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (470)   
   RefGene (8)   
Protein sequence (19)   
   UniProt (18)   
   SWISS-PROT (1)   
DNA sequence (2)   
   GenBank (1)   
   EMBL (1)   
Protein domain (1)   
   InterPro (1)   
All databases (508)   

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