Entry
Name
methanol O-anthraniloyltransferase;
AMAT;
anthraniloyl-coenzyme A (CoA):methanol acyltransferase
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
BRITE hierarchy
Sysname
anthraniloyl-CoA:methanol O-anthraniloyltransferase
Reaction(IUBMB)
anthraniloyl-CoA + methanol = CoA + O-methyl anthranilate [RN:
R10681 ]
Reaction(KEGG)
Substrate
Product
Comment
The enzyme from Concord grape (Vitis labrusca) is solely responsible for the production of O-methyl anthranilate, an important aroma and flavor compound in the grape. The enzyme has a broad substrate specificity, and can use a range of alcohols with substantial activity, the best being butanol, benzyl alcohol, iso-pentanol, octanol and 2-propanol. It can use benzoyl-CoA and acetyl-CoA as acyl donors with lower efficiency. In addition to O-methyl anthranilate, the enzyme might be responsible for the production of ethyl butanoate, methyl-3-hydroxy butanoate and ethyl-3-hydroxy butanoate, which are present in large quantities in the grapes. Also catalyses EC
2.3.1.196 , benzyl alcohol O-benzoyltransferase.
History
EC 2.3.1.232 created 2014
Orthology
K19861 benzyl alcohol O-benzoyltransferase
Genes
CSAT : 104706051 104706052 104735796 104735797 104770061 104770062
PVY : 116108988 116109446 116111856 116120760 116132506 116134533 116143617
MINC : 123202107 123205894 123206522 123206984 123209065 123209066 123209718 123226548
TPRA : 123892364 123908484 123908494 123908514
PSAT : 127093140 127093155 127093156 127093157 127093158 127095106 127095109 127095110 127095111
AHF : 112695465 112707618 112758228 112771083
LANG : 109325685 109352521
PDUL : 117621834 117628550 117637259
MSYL : 126583181 126592750 126614049 126614050 126614301 126625926 126625939 126625940 126627101 126627102 126627103
MNT : 112091470 21405595 21409773 21409849
CSAV : 115700764 115715775 115717037 115725665 115725666
BHJ : 120087706 120087771 120087980 120088300 120088899 120089052 120089185 120089279 120089324
CMAX : 111484237 111499875
CMOS : 111448233 111451858
CPEP : 111776990 111794567
POP : 18104173 18110648 7482422 7491087 7491394 7491399 7491401
PEU : 105114396 105114397 105117135 105137147
PALZ : 118027786 118027997 118032160 118032162 118032163 118032164 118035537 118038636 118046065 118046104 118046105 118052585 118053573 118053577 118059527 118061191
JRE : 108980409 108980410 108980636 108980779 108988616 108996627 109007491 109007493
CILL : 122310877 122312541 122312915 122312983 122313032 122314008
QSU : 111989464 111989482 111989491 111989496 111989499 112009113 112028909 112029064 112029458 112038642 112038657
QLO : 115959143 115959195 115960571 115960624 115960709 115961354 115961355 115961793 115962116 115962253 115970909 115972495
TWL : 119997464 120016514 120016515 120016516
VVI : 100243166 100252759 100257911 100260288 100261281 100263045 100266675
VRI : 117909762 117910166 117922686 117927476 117928444 117928972 117929179 117934012 117934019 117934029 117934038 117934171
SPEN : 107024327 107024360
SSTN : 125877106 125877107
NTA : 107776214 107814928(hsr201) 107824435
INI : 109155691 109156148 109164130 109164131 109187227 109187325
ITR : 115995617 116009674 116009683 116009684 116010715 116011308 116011310 116011311 116026764 116027563 116027719 116028080 116031593
EGT : 105953381 105953385 105953388 105953391 105953392 105961158 105969782
SSPL : 121763559 121763571 121763620 121778555 121781376 121781377 121783629 121784371 121785783 121785886
APAN : 127242310 127242362 127250396 127250430
ECAD : 122581843 122582139 122582266 122582887 122582986 122583605 122599756 122602110 122602247 122602260
CSIN : 114261072 114263020 114263029 114263031 114264229 114268121 114279762 114290041 114290110 114303439 114305119 114323378
MING : 122057711 122072760 122073246 122074738 122081117
TSS : 122644555 122648611 122657503 122659087 122659319
OSA : 4326476 4337762 4342032 4342820 4343545 4348049 4348247 4349050
DOSA : Os06t0710700-01(Os06g0710700) Os07t0550600-01(Os07g0550600) Os10t0133500-01(Os10g0133500) Os10t0195600-01(Os10g0195600)
OBR : 102708653 102714107 102714387 102720062
OGL : 127775670 127780481 127786156 127786235 127786258
BDI : 100827400 100830188 100843790
ATS : 109735002 109738690 109745656 109751661 109755369 109755385 109767173 109768200
TDC : 119271002 119280655 119283947 119289958 119294040 119298555 119316564 119327333 119331165 119332352 119335476 119338270 119345240
TAES : 123048034 123057108 123077894 123083508 123083515 123084277 123084464 123084848 123089363 123100722 123107713 123108535 123123223 123125445 123125446 123134501 123148512 123151462 123152503 123156821 123162391 123162847 123163757 123167869 123168415 123169258 123170127 123180371 123181204 123182127
TUA : 125505952 125509205 125509232 125515739 125522900 125523887 125523965 125524526 125525112 125525135 125532885 125535574 125554279 125556613
LPER : 127297255 127298411 127302869 127302889 127302940 127302943 127303689 127312935 127313174 127348516
SBI : 8064973 8065604 8065605 8067081
ZMA : 100286158 103626437 103653280
SITA : 101759181 101771750 101772151 101778271 101785522
SVS : 117835585 117840614 117840719 117851806 117854030
PVIR : 120643935 120644192 120644514 120646157 120646280 120648707 120650591 120651282 120666063 120666074 120668767 120669498 120678255 120686181 120687926 120691992 120692300 120692871 120699328 120699331 120699332 120704449
PHAI : 112876639 112889564 112890226
ZOF : 121967089 121970577 121972616 121972619 121972620 121973553 121973555 121977754 121977755 121977758 121977759 121978430 122002029 122006282 122032722 122034672
» show all
Taxonomy
Reference
Authors
Wang J, De Luca V
Title
The biosynthesis and regulation of biosynthesis of Concord grape fruit esters, including 'foxy' methylanthranilate.
Journal
Sequence
Other DBs
ExPASy - ENZYME nomenclature database: 2.3.1.232