KEGG ENZYME: 2.4.1.299

ENZYME: 2.4.1.299

Entry

EC 2.4.1.299                Enzyme

Name

cyanidin 3-O-glucoside 5-O-glucosyltransferase (acyl-glucose);
AA5GT

Class

Transferases;
Glycosyltransferases;
Hexosyltransferases

Sysname

1-O-sinapoyl-beta-D-glucose:cyanidin-3-O-beta-D-glucoside 5-O-beta-D-glucosyltransferase

Reaction(IUBMB)

1-O-sinapoyl-beta-D-glucose + cyanidin 3-O-beta-D-glucoside = sinapate + cyanidin 3,5-di-O-beta-D-glucoside [RN:R10261]

Reaction(KEGG)

R10261;
(other) R10298 R10299

Substrate

1-O-sinapoyl-beta-D-glucose [CPD:C01175];
cyanidin 3-O-beta-D-glucoside [CPD:C08604]

Product

sinapate [CPD:C00482];
cyanidin 3,5-di-O-beta-D-glucoside [CPD:C08639]

Comment

Isolated from the plant Dianthus caryophyllus (carnation). Also acts on other anthocyanidins and with other acyl-glucose donors. cf. EC 2.4.1.298, anthocyanidin 3-O-glucoside 5-O-glucosyltransferase.

History

EC 2.4.1.299 created 2013

Pathway

ec00942

Anthocyanin biosynthesis

ec01110

Biosynthesis of secondary metabolites

Orthology

K17194

cyanidin 3-O-glucoside 5-O-glucosyltransferase (acyl-glucose)

Reference

1 [PMID:20971893]

Authors

Matsuba Y, Sasaki N, Tera M, Okamura M, Abe Y, Okamoto E, Nakamura H, Funabashi H, Takatsu M, Saito M, Matsuoka H, Nagasawa K, Ozeki Y

Title

A novel glucosylation reaction on anthocyanins catalyzed by acyl-glucose-dependent glucosyltransferase in the petals of carnation and delphinium.

Journal

Plant Cell 22:3374-89 (2010)
DOI:10.1105/tpc.110.077487

Sequence

[ag:BAJ33501]

Reference

2 [PMID:22048706]

Authors

Nishizaki Y, Matsuba Y, Okamoto E, Okamura M, Ozeki Y, Sasaki N

Title

Structure of the acyl-glucose-dependent anthocyanin 5-O-glucosyltransferase gene in carnations and its disruption by transposable elements in some varieties.

Journal

Mol Genet Genomics 286:383-94 (2011)
DOI:10.1007/s00438-011-0655-7

Sequence

[ag:BAJ33501]

Other DBs

ExplorEnz - The Enzyme Database:

2.4.1.299

IUBMB Enzyme Nomenclature:

2.4.1.299

ExPASy - ENZYME nomenclature database:

2.4.1.299

BRENDA, the Enzyme Database:

2.4.1.299

DBGET integrated database retrieval system