KEGG   ENZYME: 4.1.1.114
Entry
EC 4.1.1.114                Enzyme                                 
Name
cis-3-alkyl-4-alkyloxetan-2-one decarboxylase;
oleB (gene name)
Class
Lyases;
Carbon-carbon lyases;
Carboxy-lyases
Sysname
cis-3-alkyl-4-alkyloxetan-2-one carboxy-lyase (cis-alkene-forming)
Reaction(IUBMB)
a cis-3-alkyl-4-alkyloxetan-2-one = a cis-alkene + CO2 [RN:R12257]
Reaction(KEGG)
R12257
Substrate
cis-3-alkyl-4-alkyloxetan-2-one [CPD:C21657]
Product
cis-alkene [CPD:C22504];
CO2 [CPD:C00011]
Comment
The enzyme, found in certain bacterial species, catalyses the last step in a pathway for the production of olefins.
History
EC 4.1.1.114 created 2018
Orthology
K22318  cis-3-alkyl-4-acyloxetan-2-one decarboxylase
K25044  cis-3-alkyl-4-acyloxetan-2-one decarboxylase / olefin beta-lactone synthetase
Genes
XFAXF_1965
XFTPD_0836(dhaA)
XFMXfasm12_1007
XFNXfasM23_0885
XFFXFLM_09860
XFLP303_04360
XFSD934_09785
XTWAB672_06655
XCCXCC0216(dhaA)
XCBXC_0226
XCAxcc-b100_0235(dhaA)
XCPXCR_4308
XCVXCV0241
XAXXACM_0221
XACXAC0235(dhaA)
XCIXCAW_00633(dhaA)
XCTJ151_00352
XCJJ158_00350
XCUJ159_00350
XCNJ169_00348
XCWJ162_00349
XCRJ163_00349
XCMJ164_00349
XCFJ172_00343
XFUXFF4834R_chr02060
XAOXAC29_01210
XOMXOO3982(XOO3982)
XOOXOO4213(dhaA)
XOPPXO_03953
XOYAZ54_02875
XORXOC_0331
XOZBE73_22765
XALXALC_3072
XSASB85_13805
XTNFD63_01105
XFRBER92_17860
XVEBJD12_13750
XPEBJD13_15875
XHRXJ27_16860
XGABI317_23605
XPHXppCFBP6546_10740(XppCFBP6546P_10740)
XVAC7V42_01010
XANAC801_01000
XARXB05_17860
XHYFZ025_08670
XCZEBN15_19075
XTHG4Q83_18945
XEUXSP_000237
XHDLMG31886_02550(oleB)
XAGHEP73_00275
XDYNYR95_01320
XASHEP74_00268
SMLSmlt0206(dhaA)
SMTSmal_0168
BUJBurJV3_0160
SMZSMD_0176(dhaA)
SACZAOT14_35120(dhaA)
STEKAXG53_15330
SRHBAY15_0299
SLMBIZ42_10290
STENCCR98_00905
STEMCLM74_00915
STESMG068_00770
SINCDAIF1_01800(dhmA_1)
SPAQSTNY_R02100
STEQICJ04_17660
SGENRKE57_00640
PSUPsesu_0123
PSUWWQ53_07295
PSDDSC_15450
PMEXH4W19_13900
PJPLAG73_18670
PDDMNQ95_05850
PWIMWN52_18405
LABLA76x_4683
LAQGLA29479_4476
LCPLC55x_0358
LGULG3211_0383
LEZGLE_0201(dhlA)
LEMLEN_4734
LMBC9I47_0305
LYTDWG18_14355
LUEDCD74_09645
LYJFKV23_00845
LSOLGOY17_18060
LSXH8B22_06715
LAREHIV01_014675
LHXLYSHEL_13650(dhaA)
LCASLYSCAS_13650(dhaA)
LCICINQ41_12455
LAVIINQ42_12085
LLZLYB30171_00150(oleB)
LAUXLA521A_36230
LYARDV84_05570
LUMCNR27_03295
LUSE5843_01170
LUGFPZ22_06740
THESFHQ07_09310
THEHG7079_01925
TCNH9L16_04235
TBVH9L17_09830
DJICH75_05945
XBAC7S18_17075
PPRPBPRA1463(PD0836)
SONSO_1743(oleB)
SDNSden_1370
SFRSfri_1366
SAZSama_1183
SBLSbal_1551
SBMShew185_1547
SBNSbal195_1581
SBPSbal223_2799
SBTSbal678_1618
SBSSbal117_1658
SBBSbal175_2781
SLOShew_1714
SPCSputcn32_1446
SHPSput200_1459
SSESsed_1511
SPLSpea_2735
SHEShewmr4_2547
SHMShewmr7_2614
SHNShewana3_2714
SHWSputw3181_2653
SHLShal_2819
SWDSwoo_3158
SWPswp_3335
SVOSVI_3044(dhaA)
SHFCEQ32_07540
SJASJ2017_1516
SPSWSps_01976
SBJCF168_07310
SMAVCFF01_10790
SHEWCKQ84_00030
SALGBS332_15300
SLJEGC82_14495
SMAIEXU30_02225
SPOLFH971_12840
SBKSHEWBE_2082(dhaA)
SKHSTH12_00742(dhaA)
SAESHBH39_06145
SLITJQC75_05800
SCAATUM17387_25570(oleB)
SPSHFM037_19445
SEURFM038_007250
SCYPJYB88_06035
SSEMJYB85_06330
SGLAFJ709_05995
SINVK8B83_10010
SXMMKD32_13220
SVMKDH10_001506
SHEJMZ182_06920
SSEHN7V09_09725
SCHKGII14_13325
SACHK0H61_11445
SAEGK0H80_08705
SDEOD0436_14495
SMESK0I73_07975
SHAOK0H81_11220
SZHK0H63_06430
SSPAK0I31_08850
SHNSK0J45_08680
SRHSK0I63_08800
SPSJK0I62_08435
SMAYK0H60_13700
SOGRA178_14655
CPSCPS_2154
COMCMT41_10380
PINPing_1998
PSYPCNPT3_05865
MYAMORIYA_1231
MOQHWV03_08490
WMAWM2015_2414
WEZIC757_04065
GAIIMCC3135_24165(acsA_2)
FCEJN531_007110
GPBHDN1F_36380
RPIRpic_3885
RPFRpic12D_3998
RWEKOL96_03780
CCUPBKK81_27825
CUPBKK80_28500
CUUBKK79_34450
BURBcep18194_B1849
BCMBcenmc03_3335
BCHBcen2424_4182
BCENDM39_6763
BCEPAPZ15_18125
BCONNL30_06045
BDFWI26_28750
BSEMWJ12_26385
BPSLWS57_18950
BSTLBBJ41_19530
BANNJFN94_23735
BARINLX30_32085
BAENL3V59_19545
BURKDM992_19340
PSPWBJG93_21315
PMEGFNZ07_14440
PBRYNDK50_12715
PPULRO07_04005
PANDDRB87_03725
HHTF506_16075
RJGCCGE525_22155
BRKCWS35_24605
BVZBRAD3257_1850
BELBE61_56860
BQBJ4P68_0039480
BAUTQA635_22135
BBRAQA636_22660
BGKIC762_18475
BPAHQA639_22830
BRAZLRP30_41635
LNEFZC33_04035
DNPN8A98_17725
JANJann_2625
SMEDJNX03_16135
POZI0K15_13405
AMYLQBD29_04720
NAOY958_08150
GEMGM21_2117
GEBGM18_2131
GURGura_2009
GEOGeob_3150
GLOGlov_2270
TAMMGEAMG1_1456
GBMGbem_2101
GBNGEOBRER4_19310(oleB)
GERKP004_09510
GSUBKP001_05685
GNTKP003_08915
GPLM1B72_11260
PPDPpro_3104
DESDSOUD_2645
DPSDP2632
DSFUWK_02996
DLMDPPLL_16320
DPRDespr_2660
DEOCAY53_08360
DOGHP555_05655
DBKDGMP_15680
DDUGF1_25100
DOLDole_2009
DATHRM2_23490(dhaA)
DTOTOL2_C24920(dgmA)
DOVDSCO28_06030(oleB)
DWDDSCW_10480(oleB)
DALKDSCA_08780(oleB)
DMLDmul_23310(dhmA)
DLIdnl_18060
DMMdnm_089150
AFWAnae109_0008
AGEAA314_09818
CFUSCYFUS_007909
VINAKJ08_2415
SAMYDB32_001123 DB32_004417
HOHHoch_6821
PCAYFRD00_01245
BBAEFRD01_17685
BBABd3151
BBATBdt_3081
BBACEP01_01055
BDZDOM22_00485
BMXBMS_0542 BMS_1440
HAXBALOs_1695(dhaA)
BSTOC0V70_08415 C0V70_09530
PSTISOO65_11665
PKBB4V02_23910
PLUTEI981_13970
DRUDesru_0090
DFGB0537_00920
MHOLK3U96_05530
NTPCRH09_23670
NAHF5544_42750
NWLNWFMUON74_70430
SGRFSGFS_081360
SAMBSAM23877_7351
SLSSLINC_3649
SNRSNOUR_07495
STRDNI25_11225
SHAWCEB94_30945 CEB94_37345
SAQUEJC51_37155
SPACB1H29_01575
SCOECP976_38590
SVDCP969_29070
SCAEIHE65_44590
SHAUK9S39_02405
KITCFP65_7004
STRIC7M71_028185
LXLKDY119_02264(oleC)
CMICMM_2154
CMHVO01_10020
CMSCMS1847
CMCCMN_02121
CCAPAES38_10520
CZHH9X71_10915
CPHAFGI33_02335
CCAFFGD68_13240
MTSMTES_0536
MCWA8L33_02695
MPALBO218_00780
MIHBJP65_04545
MLVCVS47_00573(acs)
MWAE4K62_15620
MLZF6J85_14990
MICSC1N74_10465
MARKQUC20_10415
RTXTI83_10140
RTCAPU90_06920
RTNA6122_2397
RRYC1O28_10935
RIAC7V51_14965
RFSC1I64_12805
RTEGSU10_02655
CUMNI26_13035
CUBBJK06_11650
CUGC1N91_13450
CQFGBG65_03450
CCITQPK07_13515
CARTPA27867_0153
CRYB7495_00675
MALKMalAC0309_0666
MYLC3E77_02030
SALAESZ53_01600
SALDFVA74_09115
PLAPEAO79_05140
MANTBHD05_11890
FRNF1C15_06375
AGXAGREI_0631
SUBTKPL76_12535
ARRARUE_c21520
ARMART_1189
ARLAFL94_04865
AREAL755_14780
AAQAOC05_09355
ARWMB46_09740
ARYATC04_12985
ARQBWQ92_22595
ACRYAC20117_20160
ARTPE5206_10070
AAGINCTC2676_1_01688(dhaA)
AAUAAur_1999
ACHAchl_0447
PSNINIBR502771_13170
AAIAARI_10560
GARAOZ07_05530
GCRGcLGCM259_0859
GLUF0M17_05205
GPRJQN66_05305
KRHKRH_10510
KPLKPaMU14_04550
KFVAS188_12305
KIIKocCE7_05290
KRSEQG70_07615
KODHBK84_05450
KVRCIB50_0002123(hcl)
MLUMlut_13240
MICKB1A86_00006575
MYUM8233_06345
RMURMDY18_08250
RDNHMPREF0733_12128
RAJRA11412_2076
RTERIDM49_05045
RAMAIDM48_05220
RKRI6G21_10205
SATKSA2016_3972
NAEBHE16_01725
BFABfae_17450
BRXBH708_04345
BRVCFK39_01160
BGGCFK41_08045
BRZCFK38_10145
BSAUDWV08_06125
BRRC1N80_10325
BRHANLU66_11215
DVADAD186_09750
DJJCOP05_06025
KSEKsed_07150
IVAIsova_0150
IDOI598_2611(lcfB_2)
SKESked_36600
CELZE5225_13970
SERJSGUI_1320
SERWFY030_02625
ORNDV701_15455
ORZFNH13_16510
BLYA2T55_16615
BLINBLSMQ_3614
BRIFDF13_04815
BLUTEW640_09555
BCAUI6G59_02570
DCOSAMEA4475696_0223(fcbA2)
GEZFE251_10285
MPHMLP_50960
MIKFOE78_05610
NMESH9L09_18015
ACTWF7P10_02425
NOABKM31_21630 BKM31_45975
NOWGBF35_34585
NCXNocox_12445(dhmA1)
NGNLCN96_30340
NMLNamu_4241
NAKEH165_06745
GOBGobs_2462
MMARMODMU_2228
KRAKrad_1681
SSYIEKG83_13735
ACTYOG774_19170
MCRAID554_00400
VERHUT12_12060
AYMYM304_23880
GLJGKIL_3487(dhaA)
CAUCaur_3533
CHLChy400_3810
CAGCagg_0552
OTEOter_3277
OBGVerru16b_02928(dhaA)
VBHCMV30_00895
OLEK0B96_08395
SLOMPXH66_08175
OBTOPIT5_15405
CAACaka_1900
RUFIK0V07_12820
PPHTGA004_15440
PUORZN69_13255
VBAIMCC26134_06605
RBARB10245(dhlA)
PSLPsta_4264
PIRVN12_03410(dhmA)
RULUC8_26870(dhlA)
RMLFF011L_52730(dhlA)
MFFMFFC18_33960(dhaA)
ROLCA51_20700(dhaA)
AHELQ31a_56320(dhaA)
LCREPla8534_51490(dhaA)
AAGGETAA8_19980(dhaA_2)
BVOPan97_23520(dhaA_2)
BREMPSR63_27700
RLCK227x_20380(dhlA)
LPAVPLANPX_0959
AMUCPan181_43850(dhaA)
PNDPla175_51970(dhaA_2)
AMOBHG15A2_09910(dhaAF)
PLMPlim_2638
PEHSpb1_34070(dhaA_1)
PBSPlabr_0345
PLSVT03_16610(dhaA_1)
PLHVT85_06225(dhaA_1)
FMRFuma_03607(dhmA)
GMRGmarT_24170(dhmA)
GIMF1728_02435
GPNPan110_23470(dhmA)
MRIMal4_31140(dhmA)
SDYNMal52_51440(dhaA_2)
PLONPla110_23370(dhaA)
GESVT84_31325(dhmA_2)
GOGC1280_33735
GMSSOIL9_84910
TIMGMBLW1_07550
LRSPX52LOC_01174
FTJFTUN_1525
ULIETAA1_41100(dhaA)
TSPHKIH39_05445
IPAIsop_2006
SACISinac_3640
PBORBSF38_04651(dhaA)
AGVOJF2_56790(dhaA_1)
UAMUABAM_06728
LPROPQO03_07060
SCORJ3U87_32900
COYHF329_05875
FPFDCC35_11385
NLIG3M70_17260
NWTNSPWAT_1579(oleB)
 » show all
Reference
1  [PMID:28029240]
  Authors
Christenson JK, Richman JE, Jensen MR, Neufeld JY, Wilmot CM, Wackett LP
  Title
beta-Lactone Synthetase Found in the Olefin Biosynthesis Pathway.
  Journal
Biochemistry 56:348-351 (2017)
DOI:10.1021/acs.biochem.6b01199
Reference
2  [PMID:28223313]
  Authors
Christenson JK, Jensen MR, Goblirsch BR, Mohamed F, Zhang W, Wilmot CM, Wackett LP
  Title
Active Multienzyme Assemblies for Long-Chain Olefinic Hydrocarbon Biosynthesis.
  Journal
J Bacteriol 199:e00890-16 (2017)
DOI:10.1128/JB.00890-16
  Sequence
[xcc:XCC0216]
Other DBs
ExplorEnz - The Enzyme Database: 4.1.1.114
IUBMB Enzyme Nomenclature: 4.1.1.114
ExPASy - ENZYME nomenclature database: 4.1.1.114
BRENDA, the Enzyme Database: 4.1.1.114

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