KEGG   ENZYME: 4.1.1.114
Entry
EC 4.1.1.114                Enzyme                                 

Name
cis-3-alkyl-4-alkyloxetan-2-one decarboxylase;
oleB (gene name)
Class
Lyases;
Carbon-carbon lyases;
Carboxy-lyases
Sysname
cis-3-alkyl-4-alkyloxetan-2-one carboxy-lyase (cis-alkene-forming)
Reaction(IUBMB)
a cis-3-alkyl-4-alkyloxetan-2-one = a cis-alkene + CO2 [RN:R12257]
Reaction(KEGG)
R12257
Substrate
cis-3-alkyl-4-alkyloxetan-2-one [CPD:C21657]
Product
alkene [CPD:C01372];
CO2 [CPD:C00011]
Comment
The enzyme, found in certain bacterial species, catalyses the last step in a pathway for the production of olefins.
History
EC 4.1.1.114 created 2018
Orthology
K22318  cis-3-alkyl-4-acyloxetan-2-one decarboxylase
K25044  cis-3-alkyl-4-acyloxetan-2-one decarboxylase / olefin beta-lactone synthetase
Genes
XFA: XF_1965
XFT: PD_0836(dhaA)
XFM: Xfasm12_1007
XFN: XfasM23_0885
XFF: XFLM_09860
XFL: P303_04360
XFS: D934_09785
XTW: AB672_06655
XCC: XCC0216(dhaA)
XCB: XC_0226
XCA: xcc-b100_0235(dhaA)
XCP: XCR_4308
XCV: XCV0241
XAX: XACM_0221
XAC: XAC0235(dhaA)
XCI: XCAW_00633(dhaA)
XOM: XOO3982(XOO3982)
XOO: XOO4213(dhaA)
XOP: PXO_03953
XOR: XOC_0331
XAL: XALC_3072
XPH: XppCFBP6546_10740(XppCFBP6546P_10740)
SML: Smlt0206(dhaA)
SMT: Smal_0168
SMZ: SMD_0176(dhaA)
SACZ: AOT14_35120(dhaA)
SINC: DAIF1_01800(dhmA_1)
PSUW: WQ53_07295
PSD: DSC_15450
LEZ: GLE_0201(dhlA)
LEM: LEN_4734
LHX: LYSHEL_13650(dhaA)
LCAS: LYSCAS_13650(dhaA)
PPR: PBPRA1463(PD0836)
SON: SO_1743(oleB)
SDN: Sden_1370
SFR: Sfri_1366
SAZ: Sama_1183
SBL: Sbal_1551
SLO: Shew_1714
SSE: Ssed_1511
SPL: Spea_2735
SHL: Shal_2819
SWD: Swoo_3158
SWP: swp_3335
SVO: SVI_3044(dhaA)
SPSW: Sps_01976
SBK: SHEWBE_2082(dhaA)
SKH: STH12_00742(dhaA)
SCAA: TUM17387_25570(oleB)
CPS: CPS_2154
PIN: Ping_1998
GAI: IMCC3135_24165(acsA_2)
RPI: Rpic_3885
BCN: Bcen_4184
BCEN: DM39_6763
BCON: NL30_06045
BSEM: WJ12_26385
BPSL: WS57_18950
PPUL: RO07_04005
GUR: Gura_2009
GLO: Glov_2270
GEO: Geob_3150
GEM: GM21_2117
GEB: GM18_2131
GBM: Gbem_2101
GBN: GEOBRER4_19310(oleB)
PPD: Ppro_3104
DPS: DP2632
DSF: UWK_02996
DOL: Dole_2009
DML: Dmul_23310(dhmA)
DAT: HRM2_23490(dhaA)
DTO: TOL2_C24920(dgmA)
DOV: DSCO28_06030(oleB)
DWD: DSCW_10480(oleB)
DALK: DSCA_08780(oleB)
DLI: dnl_18060
HOH: Hoch_6821
JAN: Jann_2625
BBA: Bd3151
BBAT: Bdt_3081
BBAC: EP01_01055
HAX: BALOs_1695(dhaA)
STRD: NI25_11225
LXL: KDY119_02264(oleC)
CMI: CMM_2154
CMS: CMS1847
CMC: CMN_02121
MTS: MTES_0536
MLV: CVS47_00573(acs)
ARM: ART_1189
AAGI: NCTC2676_1_01688(dhaA)
AAU: AAur_1999
ACH: Achl_0447
KRH: KRH_10510
KVR: CIB50_0002123(hcl)
IDO: I598_2611(lcfB_2)
SERJ: SGUI_1320
BLIN: BLSMQ_3614
DCO: SAMEA4475696_0223(fcbA2)
MPH: MLP_50960
NCX: Nocox_12445(dhmA1)
NML: Namu_4241
GOB: Gobs_2462
MMAR: MODMU_2228
KRA: Krad_1681
GLJ: GKIL_3487(dhaA)
CAU: Caur_3533
CAG: Cagg_0552
OTE: Oter_3277
OBG: Verru16b_02928(dhaA)
CAA: Caka_1900
RBA: RB10245(dhlA)
PSL: Psta_4264
PIR: VN12_03410(dhmA)
RUL: UC8_26870(dhlA)
RML: FF011L_52730(dhlA)
MFF: MFFC18_33960(dhaA)
ROL: CA51_20700(dhaA)
AHEL: Q31a_56320(dhaA)
LCRE: Pla8534_51490(dhaA)
AAGG: ETAA8_19980(dhaA_2)
BVO: Pan97_23520(dhaA_2)
RLC: K227x_20380(dhlA)
AMUC: Pan181_43850(dhaA)
PND: Pla175_51970(dhaA_2)
AMOB: HG15A2_09910(dhaAF)
PLM: Plim_2638
PEH: Spb1_34070(dhaA_1)
PLS: VT03_16610(dhaA_1)
PLH: VT85_06225(dhaA_1)
FMR: Fuma_03607(dhmA)
GMR: GmarT_24170(dhmA)
GPN: Pan110_23470(dhmA)
MRI: Mal4_31140(dhmA)
SDYN: Mal52_51440(dhaA_2)
PLON: Pla110_23370(dhaA)
GES: VT84_31325(dhmA_2)
FTJ: FTUN_1525
ULI: ETAA1_41100(dhaA)
IPA: Isop_2006
SACI: Sinac_3640
PBOR: BSF38_04651(dhaA)
AGV: OJF2_56790(dhaA_1)
 » show all
Reference
1  [PMID:28029240]
  Authors
Christenson JK, Richman JE, Jensen MR, Neufeld JY, Wilmot CM, Wackett LP
  Title
beta-Lactone Synthetase Found in the Olefin Biosynthesis Pathway.
  Journal
Biochemistry 56:348-351 (2017)
DOI:10.1021/acs.biochem.6b01199
Reference
2  [PMID:28223313]
  Authors
Christenson JK, Jensen MR, Goblirsch BR, Mohamed F, Zhang W, Wilmot CM, Wackett LP
  Title
Active Multienzyme Assemblies for Long-Chain Olefinic Hydrocarbon Biosynthesis.
  Journal
J Bacteriol 199:e00890-16 (2017)
DOI:10.1128/JB.00890-16
  Sequence
[xcc:XCC0216]
Other DBs
ExplorEnz - The Enzyme Database: 4.1.1.114
IUBMB Enzyme Nomenclature: 4.1.1.114
ExPASy - ENZYME nomenclature database: 4.1.1.114
BRENDA, the Enzyme Database: 4.1.1.114

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