KEGG   ENZYME: 4.2.1.174Help
Entry
EC 4.2.1.174                Enzyme                                 

Name
peregrinol diphosphate synthase;
MvCPS1
Class
Lyases;
Carbon-oxygen lyases;
Hydro-lyases
BRITE hierarchy
Sysname
geranylgeranyl-diphosphate hydro-lyase (peregrinol diphosphate forming)
Reaction(IUBMB)
peregrinol diphosphate = geranylgeranyl diphosphate + H2O [RN:R11821]
Reaction(KEGG)
Substrate
peregrinol diphosphate [CPD:C21658]
Product
geranylgeranyl diphosphate [CPD:C00353];
H2O [CPD:C00001]
Comment
Isolated from the plant Marrubium vulgare (white horehound). Involved in marrubiin biosynthesis.
History
EC 4.2.1.174 created 2017
Reference
1  [PMID:24990389]
  Authors
Zerbe P, Chiang A, Dullat H, O'Neil-Johnson M, Starks C, Hamberger B, Bohlmann J
  Title
Diterpene synthases of the biosynthetic system of medicinally active diterpenoids in Marrubium vulgare.
  Journal
Plant J 79:914-27 (2014)
DOI:10.1111/tpj.12589
  Sequence
Other DBs
ExplorEnz - The Enzyme Database: 4.2.1.174
IUBMB Enzyme Nomenclature: 4.2.1.174
ExPASy - ENZYME nomenclature database: 4.2.1.174
BRENDA, the Enzyme Database: 4.2.1.174

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