Lyases;
Carbon-oxygen lyases;
Acting on phosphates
BRITE hierarchy

geranyl-diphosphate diphosphate-lyase [cyclizing, (-)-camphene-forming]

geranyl diphosphate = (-)-camphene + diphosphate [RN:R09972]

R09972
Reaction

geranyl diphosphate [CPD:C00341]

(-)-Camphene is the major product in Abies grandis (grand fir) with traces of other monoterpenoids [1]. In Pseudotsuga menziesii (Douglas-fir) there are about equal parts of (-)-camphene and (-)-alpha-pinene with traces of four other monoterpenoids [2,3]. In Solanum lycopersicum (tomato) tricyclene, beta-myrcene, limonene, and traces of several other monoterpenoids are also formed [4]. See also EC 4.2.3.15 myrcene synthase, EC 4.2.3.16 (4S)-limonene synthase, EC 4.2.3.119 (-)-alpha-pinene synthase and EC 4.2.3.105 tricyclene synthase.

EC 4.2.3.117 created 2012

1  [PMID:10441373]

Bohlmann J, Phillips M, Ramachandiran V, Katoh S, Croteau R

cDNA cloning, characterization, and functional expression of four new monoterpene synthase members of the Tpsd gene family from grand fir (Abies grandis).

Arch Biochem Biophys 368:232-43 (1999)
DOI:10.1006/abbi.1999.1332

[ag:AAB70707]

2  [PMID:15921711]

Huber DP, Philippe RN, Godard KA, Sturrock RN, Bohlmann J

Characterization of four terpene synthase cDNAs from methyl jasmonate-induced Douglas-fir, Pseudotsuga menziesii.

Phytochemistry 66:1427-39 (2005)
DOI:10.1016/j.phytochem.2005.04.030

3  [PMID:15978541]

Hyatt DC, Croteau R

Mutational analysis of a monoterpene synthase reaction: altered catalysis through directed mutagenesis of (-)-pinene synthase from Abies grandis.

Arch Biochem Biophys 439:222-33 (2005)
DOI:10.1016/j.abb.2005.05.017

4  [PMID:21813655]

Falara V, Akhtar TA, Nguyen TT, Spyropoulou EA, Bleeker PM, Schauvinhold I, Matsuba Y, Bonini ME, Schilmiller AL, Last RL, Schuurink RC, Pichersky E

The tomato terpene synthase gene family.

Plant Physiol 157:770-89 (2011)
DOI:10.1104/pp.111.179648

[sly:101245212]