KEGG   ENZYME: 4.2.3.167Help
Entry
EC 4.2.3.167                Enzyme                                 

Name
dolabella-3,7-dien-18-ol synthase;
TPS20 (gene name)
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
BRITE hierarchy
Sysname
geranylgeranyl-diphosphate diphosphate-lyase [cyclizing, (3E,7E)-dolabella-3,7-dien-18-ol-forming]
Reaction(IUBMB)
geranylgeranyl diphosphate + H2O = (3E,7E)-dolabella-3,7-dien-18-ol + diphosphate [RN:R11832]
Reaction(KEGG)
Substrate
geranylgeranyl diphosphate [CPD:C00353];
H2O [CPD:C00001]
Product
(3E,7E)-dolabella-3,7-dien-18-ol [CPD:C21687];
diphosphate [CPD:C00013]
Comment
Isolated from an ecotype of the plant Arabidopsis thaliana from Cape Verde Islands. The enzyme also gives (3E,7E)-dolathalia-3,7,11-triene and traces of other terpenoids. cf. EC 4.2.3.168 dolathalia-3,7,11-triene synthase.
History
EC 4.2.3.167 created 2017
Reference
1  [PMID:27933080]
  Authors
Wang Q, Jia M, Huh JH, Muchlinski A, Peters RJ, Tholl D
  Title
Identification of a Dolabellane Type Diterpene Synthase and other Root-Expressed  Diterpene Synthases in Arabidopsis.
  Journal
Front Plant Sci 7:1761 (2016)
DOI:10.3389/fpls.2016.01761
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.167
IUBMB Enzyme Nomenclature: 4.2.3.167
ExPASy - ENZYME nomenclature database: 4.2.3.167
BRENDA, the Enzyme Database: 4.2.3.167

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