KEGG   ENZYME: 4.2.3.168Help
Entry
EC 4.2.3.168                Enzyme                                 

Name
dolathalia-3,7,11-triene synthase;
TPS20 (gene name)
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
BRITE hierarchy
Sysname
geranylgeranyl-diphosphate diphosphate-lyase [cyclizing, (3E,7E)-dolathalia-3,7,11-triene-forming]
Reaction(IUBMB)
geranylgeranyl diphosphate = (3E,7E)-dolathalia-3,7,11-triene + diphosphate [RN:R11833]
Reaction(KEGG)
Substrate
geranylgeranyl diphosphate [CPD:C00353]
Product
(3E,7E)-dolathalia-3,7,11-triene [CPD:C21688];
diphosphate [CPD:C00013]
Comment
Isolated from an ecotype of the plant Arabidopsis thaliana from Cape Verde Islands. The enzyme also gives (3E,7E)-dolabella-3,7-dien-18-ol and traces of other terpenoids. cf. EC 4.2.3.167 dolabella-3,7-dien-18-ol synthase.
History
EC 4.2.3.168 created 2017
Reference
1  [PMID:27933080]
  Authors
Wang Q, Jia M, Huh JH, Muchlinski A, Peters RJ, Tholl D
  Title
Identification of a Dolabellane Type Diterpene Synthase and other Root-Expressed  Diterpene Synthases in Arabidopsis.
  Journal
Front Plant Sci 7:1761 (2016)
DOI:10.3389/fpls.2016.01761
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.168
IUBMB Enzyme Nomenclature: 4.2.3.168
ExPASy - ENZYME nomenclature database: 4.2.3.168
BRENDA, the Enzyme Database: 4.2.3.168

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