KEGG   ENZYME: 4.2.3.178
Entry
EC 4.2.3.178                Enzyme                                 

Name
stellata-2,6,19-triene synthase
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
(2E,6E,10E,14E)-geranylfarnesyl-diphosphate diphosphate-lyase (cylizing, stellata-2,6,19-triene-forming)
Reaction(IUBMB)
(2E,6E,10E,14E)-geranylfarnesyl diphosphate = stellata-2,6,19-triene + diphosphate [RN:R11843]
Reaction(KEGG)
R11843
Substrate
(2E,6E,10E,14E)-geranylfarnesyl diphosphate [CPD:C04217]
Product
stellata-2,6,19-triene [CPD:C21703];
diphosphate [CPD:C00013]
Comment
Isolated from the fungus Aspergillus stellatus.
History
EC 4.2.3.178 created 2017
Reference
1  [PMID:26351860]
  Authors
Matsuda Y, Mitsuhashi T, Quan Z, Abe I
  Title
Molecular Basis for Stellatic Acid Biosynthesis: A Genome Mining Approach for Discovery of Sesterterpene Synthases.
  Journal
Org Lett 17:4644-7 (2015)
DOI:10.1021/acs.orglett.5b02404
  Sequence
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.178
IUBMB Enzyme Nomenclature: 4.2.3.178
ExPASy - ENZYME nomenclature database: 4.2.3.178
BRENDA, the Enzyme Database: 4.2.3.178

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