KEGG   ENZYME: 4.2.3.197
Entry
EC 4.2.3.197                Enzyme                                 
Name
eudesmane-5,11-diol synthase;
ZmEDS (gene name)
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
(2E,6E)-farnesyl-diphosphate diphosphate-lyase (cyclizing, 7-epi-ent-eudesmane-5,11-diol-forming)
Reaction(IUBMB)
(2E,6E)-farnesyl diphosphate + 2 H2O = 7-epi-ent-eudesmane-5,11-diol + diphosphate [RN:R12259]
Reaction(KEGG)
R12259
Substrate
(2E,6E)-farnesyl diphosphate [CPD:C00448];
H2O [CPD:C00001]
Product
7-epi-ent-eudesmane-5,11-diol [CPD:C22043];
diphosphate [CPD:C00013]
Comment
Isolated from the plant Zea mays (maize). The product is named in the reference using a different numbering scheme for eudesmane.
History
EC 4.2.3.197 created 2018
Orthology
K23754  eudesmane-5,11-diol synthase
Genes
OSA: 107276496 4332889 4332895 9272299
DOSA: Os03g0361100 Os03g0361500 Os03g0361700
OBR: 102708323
OGL: 127765473 127765474 127765475 127765476 127766255 127767949
BDI: 100837490
ATS: 109754902 109774711
TDC: 119270962 119279075 119281968 119281970 119298457
TAES: 123066184 123066185 123076817 123076819 123108406
TUA: 125511462 125529558 125546462 125552526
HVG: 123442521 123442523
LPER: 127338335
LRD: 124663865 124664207 124664526 124681736
SBI: 8060579 8064774 8065973 8080793 8083139
ZMA: 100281754 103640304 103646867
MFLO: 136469184 136472261 136501557 136539821 136539947 136539949
SITA: 101755067 101756327 101756584 101765119
SVS: 117833555 117865138
PVIR: 120652279 120690259 120690260
PHAI: 112872404 112901180 112903757
PAUA: 133910559
 » show all
Reference
1  [PMID:29570233]
  Authors
Liang J, Liu J, Brown R, Jia M, Zhou K, Peters RJ, Wang Q
  Title
Direct production of dihydroxylated sesquiterpenoids by a maize terpene synthase.
  Journal
Plant J 94:847-856 (2018)
DOI:10.1111/tpj.13901
  Sequence
[zma:100281754]
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.197
IUBMB Enzyme Nomenclature: 4.2.3.197
ExPASy - ENZYME nomenclature database: 4.2.3.197
BRENDA, the Enzyme Database: 4.2.3.197

  All links  
Protein sequence (5)   
   UniProt (2)   
   SWISS-PROT (2)   
   RefSeq(pep) (1)   
DNA sequence (1)   
   RefSeq(nuc) (1)   
All databases (6)   

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