KEGG   ENZYME: 4.2.3.197
Entry
EC 4.2.3.197                Enzyme                                 

Name
eudesmane-5,11-diol synthase;
ZmEDS (gene name)
Class
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
Sysname
(2E,6E)-farnesyl-diphosphate diphosphate-lyase (cyclizing, 7-epi-ent-eudesmane-5,11-diol-forming)
Reaction(IUBMB)
(2E,6E)-farnesyl diphosphate + 2 H2O = 7-epi-ent-eudesmane-5,11-diol + diphosphate [RN:R12259]
Reaction(KEGG)
R12259
Substrate
(2E,6E)-farnesyl diphosphate [CPD:C00448];
H2O [CPD:C00001]
Product
7-epi-ent-eudesmane-5,11-diol [CPD:C22043];
diphosphate [CPD:C00013]
Comment
Isolated from the plant Zea mays (maize). The product is named in the reference using a different numbering scheme for eudesmane.
History
EC 4.2.3.197 created 2018
Orthology
K23754  eudesmane-5,11-diol synthase
Genes
BNA: 106393307 106413493
OSA: 4332889 4332895 9272299
DOSA: Os03t0361100-00(Os03g0361100) Os03t0361600-00(Os03g0361600) Os03t0361700-00(Os03g0361700) Os03t0362500-00(Os03g0362500)
OBR: 102708323
BDI: 100837490
ATS: 109754902 109774711
TDC: 119270962 119279075 119281968 119281970 119298457
TAES: 123066184 123066185 123076817 123076819 123108406
SBI: 8060579 8064774 8065973 8080793 8083139
ZMA: 100281754 103640304 103646867
 » show all
Reference
1  [PMID:29570233]
  Authors
Liang J, Liu J, Brown R, Jia M, Zhou K, Peters RJ, Wang Q
  Title
Direct production of dihydroxylated sesquiterpenoids by a maize terpene synthase.
  Journal
Plant J 94:847-856 (2018)
DOI:10.1111/tpj.13901
  Sequence
[zma:100281754]
Other DBs
ExplorEnz - The Enzyme Database: 4.2.3.197
IUBMB Enzyme Nomenclature: 4.2.3.197
ExPASy - ENZYME nomenclature database: 4.2.3.197
BRENDA, the Enzyme Database: 4.2.3.197

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