| Entry |
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| Name |
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| Class |
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
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| Sysname |
(2E,6E)-farnesyl-diphosphate diphosphate-lyase (longifolene-forming)
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| Reaction(IUBMB) |
(2E,6E)-farnesyl diphosphate = longifolene + diphosphate [RN: R08542]
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| Reaction(KEGG) |
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| Substrate |
(2E,6E)-farnesyl diphosphate [CPD: C00448]
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| Product |
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| Comment |
As well as 61% longifolene the enzyme gives 15% of alpha-longipinene, 6% longicyclene and traces of other sesquiterpenoids.
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| History |
EC 4.2.3.58 created 2011
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| Pathway |
| ec00909 | Sesquiterpenoid and triterpenoid biosynthesis |
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| Orthology |
| K14185 | longifolene/alpha-longipinene synthase |
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| Reference |
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| Authors |
Martin DM, Faldt J, Bohlmann J |
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| Title |
Functional characterization of nine Norway Spruce TPS genes and evolution of gymnosperm terpene synthases of the TPS-d subfamily. |
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| Journal |
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| Sequence |
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| Other DBs |
| ExplorEnz - The Enzyme Database: | 4.2.3.58 |
| ExPASy - ENZYME nomenclature database: | 4.2.3.58 |
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