Entry |
|
Name |
5-epi-alpha-selinene synthase;
8a-epi-alpha-selinene synthase;
NP1
|
Class |
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
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Sysname |
(2E,6E)-farnesyl-diphosphate diphosphate-lyase (cyclizing, 5-epi-alpha-selinene-forming)
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Reaction(IUBMB) |
(2E,6E)-farnesyl diphosphate = 5-epi-alpha-selinene + diphosphate [RN: R09890]
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Reaction(KEGG) |
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Substrate |
(2E,6E)-farnesyl diphosphate [CPD: C00448]
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Product |
|
Comment |
Requires Mg2+. The enzyme forms 5-epi-alpha-selinene possibly via germecrene A or a 1,6-hydride shift mechanism.
|
History |
EC 4.2.3.90 created 2011
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Pathway |
ec00909 | Sesquiterpenoid and triterpenoid biosynthesis |
|
Orthology |
K18109 | 5-epi-alpha-selinene synthase |
|
Genes |
SXT: | KPP03845_106286(cyc2_2) | » show all
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Reference |
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Authors |
Agger SA, Lopez-Gallego F, Hoye TR, Schmidt-Dannert C |
Title |
Identification of sesquiterpene synthases from Nostoc punctiforme PCC 73102 and Nostoc sp. strain PCC 7120. |
Journal |
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Sequence |
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Other DBs |
ExplorEnz - The Enzyme Database: | 4.2.3.90 |
ExPASy - ENZYME nomenclature database: | 4.2.3.90 |
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