KEGG   ENZYME: 5.3.99.6
Entry
EC 5.3.99.6                 Enzyme                                 
Name
allene-oxide cyclase
Class
Isomerases;
Intramolecular oxidoreductases;
Other intramolecular oxidoreductases
Sysname
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate isomerase (cyclizing)
Reaction(IUBMB)
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate = (15Z)-12-oxophyto-10,15-dienoate [RN:R03402]
Reaction(KEGG)
R03402
Substrate
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate [CPD:C04672]
Product
(15Z)-12-oxophyto-10,15-dienoate [CPD:C01226]
Comment
Allene oxides formed by the action of EC 4.2.1.92 hydroperoxide dehydratase, are converted into cyclopentenone derivatives.
History
EC 5.3.99.6 created 1992
Pathway
ec00592  alpha-Linolenic acid metabolism
ec01100  Metabolic pathways
ec01110  Biosynthesis of secondary metabolites
Orthology
K10525  allene oxide cyclase
Genes
ATHAT1G13280(AOC4) AT3G25760(AOC1) AT3G25770(AOC2) AT3G25780(AOC3)
ALY9311345 9311346 9311347 9326060
CRB17885022 17885176 17885278 17897897
CSAT104710341 104710342 104710345 104710348 104714963 104739983 104755611 104772239 104779760 104779762 104779776 104790190 104790191 104790194
EUSEUTSA_v10004810mg EUTSA_v10004824mg EUTSA_v10008630mg
BRP103836113 103839361 103839364 103875352 103875422
BNA106350926 106350927 106352449 106362074 106382355 106409047 106416449 106416621 106437957 106443552
BOE106304493 106305039 106312059 106313826 106316858
RSZ108822889 108825544 108827249 108852447 108853876
THJ104805247 104824037 104825709
CPAP110807225
CIT102622584 102622874 102623756
CICCICLE_v10012528mg CICLE_v10012552mg CICLE_v10032510mg
PVY116107479 116113804
MINC123197606 123213654 123215880
TCC18602090 18607697 18610534
GRA105764558 105790379 105790380 105790381
GHI107916767 107916775 107916790 107946443 121202816 121204899 121204900 121204901 121220211
GAB108469180 108469715 108469716 108469717 108480614
DZI111287431 111288129 111313644 111318404
EGR104433300 104449414
GMX100775373(AOC1) 100795498(AOC3) 100800036 100803536(AOC5) 100803666(AOC4) 100805194(AOC6)
GSJ114382466 114385835 114394448 114400423 114413802 114423435
PVUPHAVU_003G111500g PHAVU_004G072000g PHAVU_008G020200g
VRA106758100 106774129 106777743
VAR108327936 108335689 108344735
VUN114174359 114182442 114183281
CCAJ109789811 109802291 109807875
APRC113862936 113867663 113868950
MTR11433162 25492710 25495597 25495598 25499834
CAM101500382 101504350
PSAT127095469 127119150 127128378 127128380
LJALj0g3v0085719.1(Lj0g3v0085719.1) Lj0g3v0299069.1(Lj0g3v0299069.1) Lj1g3v4590880.1(Lj1g3v4590880.1) Lj2g3v1168900.1(Lj2g3v1168900.1)
ADU107471452 107472554 107473823 107486497 107491290
AIP107614735 107623642 107635545 107643776
AHF112716691 112728907 112740621 112744732 112750538 112777788 112783372 112798019 112802681
LANG109326575 109335008 109347405 109353304 109354114 109355798 109359238
FVE101294384 101305363 101311343
RCN112180867 112188761 112197345
PPER18783318 18788592
PMUM103329664 103341439
PAVI110748489 110757131 110758230 110759708
PDUL117621021 117627108
MDM103402724 103411240 103423658 103433988 103451672
PXB103929185 103947146 103947801
ZJU107416556 107416558 107429485
MNT21392028 21405757
CSV101213826 101222233
CMO103498591 103503379
BHJ120080421 120092575
MCHA111006717
CMAX111472108 111486971 111489456
CMOS111445098 111445257 111458193
CPEP111784509 111788683 111808599
RCU8269521 8287246
JCU105638701(AOC) 105641985
HBR110642011 110642243 110643837 110656018
MESC110600311 110609890 110631034
POP18107399 7483932 7494544
PEU105110920 105123352 105123721
PALZ118029685 118056003
JRE108987084 109002736 109002750
QSU112015604 112015605 112015607 112025648
QLO115975827 115975828 115975829 115988347
TWL119992308 120001774 120016275
VVI100232990 100257779
VRI117913924 117931254
SLY544306(AOC)
SPEN107008741
SOT102577822
SSTN125848995
CANN107854684
NTA107767576 107768393(aoc)
NSY104238154
NTO104120106(AOC)
NAU109240002
INI109151137 109168506(AOC)
ITR116011942 116019329
SIND105162178 105177957
OEU111382804 111399032
EGT105965943 105966076 105974425
SSPL121749627 121767287 121769720 121787779
APAN127242326 127248592 127264233
HAN110889417 110902211 110908787 110911893
ECAD122589871
LSV111901841
CCAV112513300 112513449 112515446
DCR108193732 108216213 108220215
CSIN114285638 114285648 114307969
BVG104905703
SOE110786866
CQI110691262 110719970 110724846 110728173 110733354 110733355
NNU104603032
MING122075712 122078647
TSS122653565 122663856
PSOM113275629 113282007
OSA4333201
DOSAOs03t0438100-01(Os03g0438100)
OBR102709159
BDI100829167
ATS109748376
TDC119318101 119323391
TAES123128593 123138464 123145716
TUA125514845
LPER127332563
SBI8063218
ZMA100273356(aoc2) 542151(aoc1)
SITA101764321
SVS117840603
PVIR120651985 120690841
PHAI112877538
PDA103709008 103722241
EGU105041662 105047523
MUS103978400 103979699 103980244 103981102
ZOF121969756 121974885 122012396 122016867
DCT110093045 110093718
PEQ110026279
AOF109847862
NCOL116249215 116263940 116263969 116264569 116264876
ATR18446965
SMOSELMODRAFT_124720 SELMODRAFT_91887
PPP112274177 112280616 112281962 112282144 112284572
 » show all
Reference
1  [PMID:3178850]
  Authors
Hamberg M.
  Title
Biosynthesis of 12-oxo-10,15(Z)-phytodienoic acid: identification of an allene oxide cyclase.
  Journal
Biochem Biophys Res Commun 156:543-50 (1988)
DOI:10.1016/S0006-291X(88)80876-3
Other DBs
ExplorEnz - The Enzyme Database: 5.3.99.6
IUBMB Enzyme Nomenclature: 5.3.99.6
ExPASy - ENZYME nomenclature database: 5.3.99.6
BRENDA, the Enzyme Database: 5.3.99.6
CAS: 118390-59-3

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